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  • A homemade fused-silica capillary dropping mercury electrode was used for the investigation of the adsorption behavior of a complex system by electrocapillary measurements. A mixture of soybean phospholipids, known as asolectin, was used for this purpose. The proposed setup with a fused-silica capillary electrode enables to observe aggregation and adsorption of asolectin aggregates at the mercury electrode surface and to determine the concentrations corresponding to the formation of asolectin micelles (critical micelle concentration, CMC) and liposomes (critical liposome concentration, CLC). Values of CMC (196.239.0 mg?L-1) and CLC (1360350 mg?L-1) were obtained from the dependence of drop time on the logarithm of asolectin concentration in phosphate buffer pH 7.0 within a concentration range from 1 to 50 mmol?L-1.
  • A homemade fused-silica capillary dropping mercury electrode was used for the investigation of the adsorption behavior of a complex system by electrocapillary measurements. A mixture of soybean phospholipids, known as asolectin, was used for this purpose. The proposed setup with a fused-silica capillary electrode enables to observe aggregation and adsorption of asolectin aggregates at the mercury electrode surface and to determine the concentrations corresponding to the formation of asolectin micelles (critical micelle concentration, CMC) and liposomes (critical liposome concentration, CLC). Values of CMC (196.239.0 mg?L-1) and CLC (1360350 mg?L-1) were obtained from the dependence of drop time on the logarithm of asolectin concentration in phosphate buffer pH 7.0 within a concentration range from 1 to 50 mmol?L-1. (en)
Title
  • Fused-Silica Capillary Dropping Mercury Electrode for Electrocapillary Measurements
  • Fused-Silica Capillary Dropping Mercury Electrode for Electrocapillary Measurements (en)
skos:prefLabel
  • Fused-Silica Capillary Dropping Mercury Electrode for Electrocapillary Measurements
  • Fused-Silica Capillary Dropping Mercury Electrode for Electrocapillary Measurements (en)
skos:notation
  • RIV/61989592:15310/13:33147371!RIV14-MSM-15310___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • P(ED2.1.00/03.0058), P(EE2.3.20.0018)
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  • 1
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  • 76053
http://linked.open...ai/riv/idVysledku
  • RIV/61989592:15310/13:33147371
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Surfactants; Phospholipids; Electrocapillary measurement; Dropping mercury electrode; Aggregation (en)
http://linked.open.../riv/klicoveSlovo
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  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [E6A0584997B4]
http://linked.open...i/riv/nazevZdroje
  • Electroanalysis
http://linked.open...in/vavai/riv/obor
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  • 25
http://linked.open...iv/tvurceVysledku
  • Barták, Petr
  • Skopalová, Jana
  • Součková, Jitka
  • Švecová, Hana
http://linked.open...ain/vavai/riv/wos
  • 000313807600022
issn
  • 1040-0397
number of pages
http://bibframe.org/vocab/doi
  • 10.1002/elan.201200382
http://localhost/t...ganizacniJednotka
  • 15310
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