About: Synthesis and X-ray structure of nickel(II) benzylpiperazine-dithiocarbamate complex [Ni(bpdtc)(PPh3)2]ClO4PPh3

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About: Synthesis and X-ray structure of nickel(II) benzylpiperazine-dithiocarbamate complex [Ni(bpdtc)(PPh3)2]ClO4PPh3 Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A mixed-ligand nickel(II) dithiocarbamate complex of the composition [Ni(bpdtc)(PPh3)2]ClO4PPh3 was synthesized, characterized (elemental analysis, UV-Vis, IR and NMR spectroscopy and molar conductivity measurements) and its X-ray structure was determined. The three ligands are arranged in a distorted square-planar geometry (an S2P2 donor set), with the bond lengths and angles within the vicinity of the central atom as follows: Ni-P = 2.2150(6) and 2.2529(6) ?, Ni-S = 2.2267(6) and 2.2129(6) ?, P-Ni-P = 105.11(2), S-Ni-S = 78.26(2). The P-Ni-P angle of the studied complex falls outside the interval of 98.37-102.92 determined for thirteen formerly reported structural analogues involving the [Ni(ndtc)(PPh3)2]+ moiety with a combination of dithiocarbamate (ndtc) and triphenylphosphine (PPh3) ligands. In the crystal, the complex cations, perchlorate anions and PPh3 molecules of crystallization are linked through intramolecular C-H...O and C-H...pi and intermolecular C-H...O, C-H...C and C-H...pi contacts to a three-dimensional architecture. A mixed-ligand nickel(II) dithiocarbamate complex of the composition [Ni(bpdtc)(PPh3)2]ClO4PPh3 was synthesized, characterized (elemental analysis, UV-Vis, IR and NMR spectroscopy and molar conductivity measurements) and its X-ray structure was determined. The three ligands are arranged in a distorted square-planar geometry (an S2P2 donor set), with the bond lengths and angles within the vicinity of the central atom as follows: Ni-P = 2.2150(6) and 2.2529(6) ?, Ni-S = 2.2267(6) and 2.2129(6) ?, P-Ni-P = 105.11(2), S-Ni-S = 78.26(2). The P-Ni-P angle of the studied complex falls outside the interval of 98.37-102.92 determined for thirteen formerly reported structural analogues involving the [Ni(ndtc)(PPh3)2]+ moiety with a combination of dithiocarbamate (ndtc) and triphenylphosphine (PPh3) ligands. In the crystal, the complex cations, perchlorate anions and PPh3 molecules of crystallization are linked through intramolecular C-H...O and C-H...pi and intermolecular C-H...O, C-H...C and C-H...pi contacts to a three-dimensional architecture. (en)
Title	Synthesis and X-ray structure of nickel(II) benzylpiperazine-dithiocarbamate complex [Ni(bpdtc)(PPh3)2]ClO4PPh3 Synthesis and X-ray structure of nickel(II) benzylpiperazine-dithiocarbamate complex [Ni(bpdtc)(PPh3)2]ClO4PPh3 (en)
skos:prefLabel	Synthesis and X-ray structure of nickel(II) benzylpiperazine-dithiocarbamate complex [Ni(bpdtc)(PPh3)2]ClO4PPh3 Synthesis and X-ray structure of nickel(II) benzylpiperazine-dithiocarbamate complex [Ni(bpdtc)(PPh3)2]ClO4PPh3 (en)
skos:notation	RIV/61989592:15310/13:33146056!RIV14-MSM-15310___
http://linked.open...avai/predkladatel	Přírodovědecká fakulta
http://linked.open...avai/riv/aktivita	P S
http://linked.open...avai/riv/aktivity	P(ED2.1.00/03.0058), P(EE2.3.20.0017), S
http://linked.open...iv/cisloPeriodika	OCT
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Trávníček, Zdeněk Štarha, Pavel Pastorek, Richard
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	109496
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/13:33146056
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Nickel(II) complex, Dithiocarbamate, Triphenylphosphine, NMR spectroscopy, X-ray structure (en)
http://linked.open.../riv/klicoveSlovo	NMR spectroscopy X-ray structure Triphenylphosphine Dithiocarbamate Nickel(II) complex
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[4FEA0D1558F1]
http://linked.open...i/riv/nazevZdroje	Journal of Molecular Structure
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Regional Centre of Advanced Technologies and Materials Research team development of the Regional Centre of Advanced Technologies and Materials
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	1049
http://linked.open...iv/tvurceVysledku	Trávníček, Zdeněk Štarha, Pavel Pastorek, Richard
http://linked.open...ain/vavai/riv/wos	000324784700004
issn	0022-2860
number of pages	5 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.molstruc.2013.06.021
http://localhost/t...ganizacniJednotka	15310

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