About: Enhanced comprehensive two-dimensional gas chromatographic resolution of polychlorinated biphenyls on a non-polar polysiloxane and an ionic liquid column series

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About: Enhanced comprehensive two-dimensional gas chromatographic resolution of polychlorinated biphenyls on a non-polar polysiloxane and an ionic liquid column series Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A total of 196 out of 209 polychlorobiphenyl (PCB) congeners were resolved using GC x GC-TOFMS with a non-polar/ionic liquid column series consisting of poly(50%-n-octyl-50%-methyl)siloxane and (1,12-di(tripropylphosphonium)dodecane bis(trifluoromethansulfonyl)amide) in the first and second dimension, respectively. It has been found that 13 PCB congeners overlap in five doublets (CB12 + CB13, CB62 +CB75, CB70 + CB76, CB97 + CB125 and CB153 +CB168) and one triplet (CB90 + CB101 + CB113). All toxic, %22dioxin like%22 congeners were separated with no interferences from any PCB congener. The 109 PCBs present in Aroclor 1242 and the 82 PCBs present in Aroclor 1260 were resolved GC x GC-TOFMS analysis on this column set. A total of 196 out of 209 polychlorobiphenyl (PCB) congeners were resolved using GC x GC-TOFMS with a non-polar/ionic liquid column series consisting of poly(50%-n-octyl-50%-methyl)siloxane and (1,12-di(tripropylphosphonium)dodecane bis(trifluoromethansulfonyl)amide) in the first and second dimension, respectively. It has been found that 13 PCB congeners overlap in five doublets (CB12 + CB13, CB62 +CB75, CB70 + CB76, CB97 + CB125 and CB153 +CB168) and one triplet (CB90 + CB101 + CB113). All toxic, %22dioxin like%22 congeners were separated with no interferences from any PCB congener. The 109 PCBs present in Aroclor 1242 and the 82 PCBs present in Aroclor 1260 were resolved GC x GC-TOFMS analysis on this column set. (en)
Title	Enhanced comprehensive two-dimensional gas chromatographic resolution of polychlorinated biphenyls on a non-polar polysiloxane and an ionic liquid column series Enhanced comprehensive two-dimensional gas chromatographic resolution of polychlorinated biphenyls on a non-polar polysiloxane and an ionic liquid column series (en)
skos:prefLabel	Enhanced comprehensive two-dimensional gas chromatographic resolution of polychlorinated biphenyls on a non-polar polysiloxane and an ionic liquid column series Enhanced comprehensive two-dimensional gas chromatographic resolution of polychlorinated biphenyls on a non-polar polysiloxane and an ionic liquid column series (en)
skos:notation	RIV/61989592:15310/11:33118054!RIV12-MSM-15310___
http://linked.open...avai/predkladatel	Přírodovědecká fakulta
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM6198959216)
http://linked.open...iv/cisloPeriodika	5
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Zapadlo, Michal
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	197593
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/11:33118054
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Aroclors; Polychlorinated biphenyls; Ionic liquid column; Time-of-flight mass spectrometry; Comprehensive two-dimensional GC (en)
http://linked.open.../riv/klicoveSlovo	Aroclors Comprehensive two-dimensional GC Ionic liquid column Time-of-flight mass spectrometry Polychlorinated biphenyls
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[F8C9D0BE46D6]
http://linked.open...i/riv/nazevZdroje	Journal of Chromatography A
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	1218
http://linked.open...iv/tvurceVysledku	Armstrong, Daniel Kovalczuk, Tomáš Krupčík, Jan Majek, Pavel Sandra, Pat Zapadlo, Michal Španík, Ivan
http://linked.open...ain/vavai/riv/wos	000286848700015
http://linked.open...n/vavai/riv/zamer	Modulation of signalling and regulatory pathways in normal and cancer cells
issn	0021-9673
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.chroma.2010.12.013
http://localhost/t...ganizacniJednotka	15310
is http://linked.open...avai/riv/vysledek of	Enhanced comprehensive two-dimensional gas chromatographic resolution of polychlorinated biphenyls on a non-polar polysiloxane and an ionic liquid column series Enhanced comprehensive two-dimensional gas chromatographic resolution of polychlorinated biphenyls on a non-polar polysiloxane and an ionic liquid column series

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