About: Nickel(IV) dithiocarbamato complexes of the [Ni(ndtc)3]X type: X-ray structure of [Ni(hmidtc)3][FeCl4]

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Fourteen octahedral Ni(IV) dithiocarbamato complexes of the general formula [Ni(ndtc)3]X.yH2O {ndtc stands for the appropriate dithiocarbamate anion, X stands for ClO4- (1-8; y = 0) or [FeCl4]- (9-14; y = 0 for 9-12, 1 for 13 and 0.5 for 14) was prepared by the oxidation of the corresponding Ni(II) complexes, i.e. [Ni(ndtc)2], with NOClO4 or FeCl3. The complexes, involving a high-valent Ni(IV)S6 core, were characterized by elemental analysis (C, H, N. Cl and Ni), UV-Vis and FTIR spectroscopy, thermal analysis and magnetochemical and conductivity measurements. The X-ray structure of {Ni(hmidtc)3][FeCl4] (9) was determined and this revealed slightly distorted octahedral and tetrahedral geometries within the complex cations, and anions, respectively. Moreover, the formal oxidation state of iron in (FeCl4]- as well as the coordination geometry in its vicinity was also proved by 57Fe Mossbauer spectroscopy in the case of 9. Fourteen octahedral Ni(IV) dithiocarbamato complexes of the general formula [Ni(ndtc)3]X.yH2O {ndtc stands for the appropriate dithiocarbamate anion, X stands for ClO4- (1-8; y = 0) or [FeCl4]- (9-14; y = 0 for 9-12, 1 for 13 and 0.5 for 14) was prepared by the oxidation of the corresponding Ni(II) complexes, i.e. [Ni(ndtc)2], with NOClO4 or FeCl3. The complexes, involving a high-valent Ni(IV)S6 core, were characterized by elemental analysis (C, H, N. Cl and Ni), UV-Vis and FTIR spectroscopy, thermal analysis and magnetochemical and conductivity measurements. The X-ray structure of {Ni(hmidtc)3][FeCl4] (9) was determined and this revealed slightly distorted octahedral and tetrahedral geometries within the complex cations, and anions, respectively. Moreover, the formal oxidation state of iron in (FeCl4]- as well as the coordination geometry in its vicinity was also proved by 57Fe Mossbauer spectroscopy in the case of 9. (en)
Title	Nickel(IV) dithiocarbamato complexes of the [Ni(ndtc)3]X type: X-ray structure of [Ni(hmidtc)3][FeCl4] Nickel(IV) dithiocarbamato complexes of the [Ni(ndtc)3]X type: X-ray structure of [Ni(hmidtc)3][FeCl4] (en)
skos:prefLabel	Nickel(IV) dithiocarbamato complexes of the [Ni(ndtc)3]X type: X-ray structure of [Ni(hmidtc)3][FeCl4] Nickel(IV) dithiocarbamato complexes of the [Ni(ndtc)3]X type: X-ray structure of [Ni(hmidtc)3][FeCl4] (en)
skos:notation	RIV/61989592:15310/11:33116864!RIV13-MSM-15310___
http://linked.open...avai/predkladatel	Přírodovědecká fakulta
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(ED2.1.00/03.0058), P(EE2.3.20.0017), Z(MSM6198959218)
http://linked.open...iv/cisloPeriodika	17
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Trávníček, Zdeněk Štarha, Pavel Pastorek, Richard
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	216024
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/11:33116864
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Spectroscopy; X-ray structure; Dithiocarbamate; Nickel(IV) complexes (en)
http://linked.open.../riv/klicoveSlovo	Spectroscopy X-ray structure Dithiocarbamate Nickel(IV) complexes
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[12FBA96A74BB]
http://linked.open...i/riv/nazevZdroje	Polyhedron
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Regional Centre of Advanced Technologies and Materials Research team development of the Regional Centre of Advanced Technologies and Materials
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	30
http://linked.open...iv/tvurceVysledku	Trávníček, Zdeněk Štarha, Pavel Pastorek, Richard Peterek, Tomáš
http://linked.open...ain/vavai/riv/wos	000296996500006
http://linked.open...n/vavai/riv/zamer	Komplexní sloučeniny a oxidy přechodných kovů s využitím v bioaplikacích a nanotechnologiích
issn	0277-5387
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.poly.2011.08.022
http://localhost/t...ganizacniJednotka	15310
is http://linked.open...avai/riv/vysledek of	Nickel(IV) dithiocarbamato complexes of the [Ni(ndtc)3]X type: X-ray structure of [Ni(hmidtc)3][FeCl4]

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