About: Experimental and Computational Study of the Structural and Electronic Properties of FeII(2,2-bipyridine)(mes)2 and [FeII(2,2-bipyridine)(mes)2]-, a Complex Containing a 2,2-Bipyridyl Radical Anion

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Experimental and Computational Study of the Structural and Electronic Properties of FeII(2,2-bipyridine)(mes)2 and [FeII(2,2-bipyridine)(mes)2]-, a Complex Containing a 2,2-Bipyridyl Radical Anion Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Addition of potassium metal and 2,2,2-crypt (4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) to a tetrahydrofuran (THF) solution of Fe(2,20-bipyridine)(mes)2 (1; mes = 2,4,6-Me3C6H2) yielded the anionic komplex [Fe(2,2-bipyridine)(mes)2]- which was isolated as [K(2,2,2-crypt)][Fe(2,2-bipyridine)(mes)2] (2) alongside the side-product [K(2,2,2-crypt)][Fe(mes)3] 3 C6H12 (3). A compositionally pure sample of 2 was obtained by dissolving a mixture of 2 and 3 in dry pyridine and layering the resulting solution with toluene. Solid state magnetic susceptibility measurements on 1 reveal Curie-Weiss paramagnetic behavior with a molar magnetic moment of 5.12(1) mýB between 20 and 300 K, a value which is in line with the expected iron(II) spin-only value of 4.90 mýB. Addition of potassium metal and 2,2,2-crypt (4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) to a tetrahydrofuran (THF) solution of Fe(2,20-bipyridine)(mes)2 (1; mes = 2,4,6-Me3C6H2) yielded the anionic komplex [Fe(2,2-bipyridine)(mes)2]- which was isolated as [K(2,2,2-crypt)][Fe(2,2-bipyridine)(mes)2] (2) alongside the side-product [K(2,2,2-crypt)][Fe(mes)3] 3 C6H12 (3). A compositionally pure sample of 2 was obtained by dissolving a mixture of 2 and 3 in dry pyridine and layering the resulting solution with toluene. Solid state magnetic susceptibility measurements on 1 reveal Curie-Weiss paramagnetic behavior with a molar magnetic moment of 5.12(1) mýB between 20 and 300 K, a value which is in line with the expected iron(II) spin-only value of 4.90 mýB. (en)
Title	Experimental and Computational Study of the Structural and Electronic Properties of FeII(2,2-bipyridine)(mes)2 and [FeII(2,2-bipyridine)(mes)2]-, a Complex Containing a 2,2-Bipyridyl Radical Anion Experimental and Computational Study of the Structural and Electronic Properties of FeII(2,2-bipyridine)(mes)2 and [FeII(2,2-bipyridine)(mes)2]-, a Complex Containing a 2,2-Bipyridyl Radical Anion (en)
skos:prefLabel	Experimental and Computational Study of the Structural and Electronic Properties of FeII(2,2-bipyridine)(mes)2 and [FeII(2,2-bipyridine)(mes)2]-, a Complex Containing a 2,2-Bipyridyl Radical Anion Experimental and Computational Study of the Structural and Electronic Properties of FeII(2,2-bipyridine)(mes)2 and [FeII(2,2-bipyridine)(mes)2]-, a Complex Containing a 2,2-Bipyridyl Radical Anion (en)
skos:notation	RIV/61989592:15310/10:10213080!RIV11-MSM-15310___
http://linked.open...avai/riv/aktivita	S
http://linked.open...avai/riv/aktivity	S
http://linked.open...iv/cisloPeriodika	13
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Herchel, Radovan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	258243
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/10:10213080
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	iron complexes, magnetic behavior (en)
http://linked.open.../riv/klicoveSlovo	magnetic behavior iron complexes
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[916AA1096E50]
http://linked.open...i/riv/nazevZdroje	Inorganic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	9 (xsd:int)
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	49
http://linked.open...iv/tvurceVysledku	Herchel, Radovan Irwin, Mark Denning, Mark Goicoechea, Jose Grandjean, Fernande Jenkins, Rhiannon Kramer, Tobias Long, Gary McGrady, John
http://linked.open...ain/vavai/riv/wos	000279211500046
issn	0020-1669
number of pages	12 (xsd:int)
http://localhost/t...ganizacniJednotka	15310
is http://linked.open...avai/riv/vysledek of	Experimental and Computational Study of the Structural and Electronic Properties of FeII(2,2-bipyridine)(mes)2 and [FeII(2,2-bipyridine)(mes)2]-, a Complex Containing a 2,2-Bipyridyl Radical Anion Experimental and Computational Study of the Structural and Electronic Properties of FeII(2,2-bipyridine)(mes)2 and [FeII(2,2-bipyridine)(mes)2]-, a Complex Containing a 2,2-Bipyridyl Radical Anion Experimental and Computational Study of the Structural and Electronic Properties of FeII(2,2-bipyridine)(mes)2 and [FeII(2,2-bipyridine)(mes)2]-, a Complex Containing a 2,2-Bipyridyl Radical Anion

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 85 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software