About: Analysis of chiral compounds using mass spectrometric approaches

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Analysis of isomers is an important task of analytical chemistry. An unquestionable number of enzymes, factors, cofactors and also other biologically important compounds are isomeric. One of the most interesting groups of isomers is the group of optical isomers. Chiral analysis is generally based on applications of separation techniques or less commonly; it is based on spectroscopic approaches. Mass spectrometry can be labeled as an interesting alternative. Several mass spectrometric methods that are able to handle enantiomeric discriminations were developed, but most of them have only one of the potentially strong approaches. This method is based on a formation of trimer diastereoisomers that are composed of analyte (one ligand), reference (2 ligands), and all three ligands are coordinated by selected bivalent metal. These trimeric clusters are generated in the ion source (usually electrospray, but nano-electrospray or DESI can be used as well). Essentially, clusters can dissociate using two dis Analysis of isomers is an important task of analytical chemistry. An unquestionable number of enzymes, factors, cofactors and also other biologically important compounds are isomeric. One of the most interesting groups of isomers is the group of optical isomers. Chiral analysis is generally based on applications of separation techniques or less commonly; it is based on spectroscopic approaches. Mass spectrometry can be labeled as an interesting alternative. Several mass spectrometric methods that are able to handle enantiomeric discriminations were developed, but most of them have only one of the potentially strong approaches. This method is based on a formation of trimer diastereoisomers that are composed of analyte (one ligand), reference (2 ligands), and all three ligands are coordinated by selected bivalent metal. These trimeric clusters are generated in the ion source (usually electrospray, but nano-electrospray or DESI can be used as well). Essentially, clusters can dissociate using two dis (en)
Title	Analysis of chiral compounds using mass spectrometric approaches Analysis of chiral compounds using mass spectrometric approaches (en)
skos:prefLabel	Analysis of chiral compounds using mass spectrometric approaches Analysis of chiral compounds using mass spectrometric approaches (en)
skos:notation	RIV/61989592:15310/09:00010511!RIV10-MSM-15310___
http://linked.open...avai/riv/aktivita	S Z
http://linked.open...avai/riv/aktivity	S, Z(MSM6198959216)
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Ranc, Václav
http://linked.open.../riv/druhVysledku	O - Ostatní výsledky nezařaditelné do žádného z výše uvedených druhů výsledku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	302828
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/09:00010511
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	mass spectrometry; chiral separation; kinetic method (en)
http://linked.open.../riv/klicoveSlovo	chiral separation mass spectrometry kinetic method
http://linked.open...ontrolniKodProRIV	[BA580B7D894A]
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	1 (xsd:int)
http://linked.open...UplatneniVysledku	2009
http://linked.open...iv/tvurceVysledku	Ranc, Václav
http://linked.open...n/vavai/riv/zamer	Modulation of signalling and regulatory pathways in normal and cancer cells
http://localhost/t...ganizacniJednotka	15310

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