About: Polyacrylate-assisted synthesis of stable copper nanoparticles and copper(I) oxide nanocubes with high catalytic efficiency     Goto   Sponge   NotDistinct   Permalink

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Description
  • The synthesis of Cu nanoparticles (NPs) via the reduction of Cu ions with sodium borohydride in the presence of sodium polyacrylate is presented. The final Cu nanocrystals having 14 nm in diameter were generated via the aggregation and coalescence of the primarily formed ultrasmall particles (approx.3 nm). Addition of sodium sulphite to the dispersions provided the protection of the Cu NPs against oxidation. On the other hand, the controlled aeration of the Cu NPs resulted in their transformation to Cu2O nanocubes with the average size of 18 nm. Both Cu NPs and Cu2O nanocubes can effectively catalyze reduction of 4-nitrophenol by sodium borohydride in aqueous solution.
  • The synthesis of Cu nanoparticles (NPs) via the reduction of Cu ions with sodium borohydride in the presence of sodium polyacrylate is presented. The final Cu nanocrystals having 14 nm in diameter were generated via the aggregation and coalescence of the primarily formed ultrasmall particles (approx.3 nm). Addition of sodium sulphite to the dispersions provided the protection of the Cu NPs against oxidation. On the other hand, the controlled aeration of the Cu NPs resulted in their transformation to Cu2O nanocubes with the average size of 18 nm. Both Cu NPs and Cu2O nanocubes can effectively catalyze reduction of 4-nitrophenol by sodium borohydride in aqueous solution. (en)
Title
  • Polyacrylate-assisted synthesis of stable copper nanoparticles and copper(I) oxide nanocubes with high catalytic efficiency
  • Polyacrylate-assisted synthesis of stable copper nanoparticles and copper(I) oxide nanocubes with high catalytic efficiency (en)
skos:prefLabel
  • Polyacrylate-assisted synthesis of stable copper nanoparticles and copper(I) oxide nanocubes with high catalytic efficiency
  • Polyacrylate-assisted synthesis of stable copper nanoparticles and copper(I) oxide nanocubes with high catalytic efficiency (en)
skos:notation
  • RIV/61989592:15310/09:00010336!RIV10-MSM-15310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(1M0512), Z(MSM6198959218), Z(MSM6198959223)
http://linked.open...iv/cisloPeriodika
  • 45
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 334138
http://linked.open...ai/riv/idVysledku
  • RIV/61989592:15310/09:00010336
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • copper; copper(I) oxide; nanoparticles; nanocubes; sodium polyacrylate; catalyst; 4-nitrophenol (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [E95DA58B17F6]
http://linked.open...i/riv/nazevZdroje
  • Journal of Materials Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 19
http://linked.open...iv/tvurceVysledku
  • Jančík, Dalibor
  • Kvítek, Libor
  • Panáček, Aleš
  • Prucek, Robert
  • Soukupová, Jana
  • Zbořil, Radek
  • Vančurová, Lenka
http://linked.open...n/vavai/riv/zamer
issn
  • 0959-9428
number of pages
http://localhost/t...ganizacniJednotka
  • 15310
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