Description
| - The following complexes [{Cu(ept)}(3) {Cr(CN)(6)}(2)]center dot 5H(2)O, [{Cu(hatce)}(3){Cr(CN)(6))2]center dot 15H(2)O, [{Cu(hatce))(3){Cr(CN)(6)}(2)]center dot 14H(2)O,[{Cu(ept)}(3){Co(CN)(6)}(2)]center dot 5H(2)O, [{Cu(hatce)}(3){Co(CN)(6)}(2)]center dot 18H(2)O and [{Cu(medpt)}(3){Co(CN)(6)}(2)]center dot H2O (ept = N-(2-aminoethyl)-1,3-propandiamine, hatce = 1,3,6,10,12,15-hexaazatricyclo [13.3.1.1(6,10)]cicosane, hatco= 1,3,6,9,11,14-hexaazatricyclo[12.2.1.1(6,9)]octadccane and medpt = N,N-bis-(3-aminopropyl) m ethyl amine) have been synthesized by the reactions Of Cu(ClO4)(2)center dot 6H(2)O or Cu(NO3)(2)center dot 3H(2)O and ept or medpt, or [Cu(hatce)](ClO4)(2)-2H(2)O and [Cu(hatco)Cl]ClO4 center dot H2O, and K-3[Cr(CN)(6)] or K-3[Co(CN)(6)] in aqueous solution, respectively. All the compounds have been characterized by elemental analyses, IR and UV-Vis spectroscopies and magnetic measurements and the three selected complexes were studied using thermal analysis. The crystal structure of [(Cu(
- The following complexes [{Cu(ept)}(3) {Cr(CN)(6)}(2)]center dot 5H(2)O, [{Cu(hatce)}(3){Cr(CN)(6))2]center dot 15H(2)O, [{Cu(hatce))(3){Cr(CN)(6)}(2)]center dot 14H(2)O,[{Cu(ept)}(3){Co(CN)(6)}(2)]center dot 5H(2)O, [{Cu(hatce)}(3){Co(CN)(6)}(2)]center dot 18H(2)O and [{Cu(medpt)}(3){Co(CN)(6)}(2)]center dot H2O (ept = N-(2-aminoethyl)-1,3-propandiamine, hatce = 1,3,6,10,12,15-hexaazatricyclo [13.3.1.1(6,10)]cicosane, hatco= 1,3,6,9,11,14-hexaazatricyclo[12.2.1.1(6,9)]octadccane and medpt = N,N-bis-(3-aminopropyl) m ethyl amine) have been synthesized by the reactions Of Cu(ClO4)(2)center dot 6H(2)O or Cu(NO3)(2)center dot 3H(2)O and ept or medpt, or [Cu(hatce)](ClO4)(2)-2H(2)O and [Cu(hatco)Cl]ClO4 center dot H2O, and K-3[Cr(CN)(6)] or K-3[Co(CN)(6)] in aqueous solution, respectively. All the compounds have been characterized by elemental analyses, IR and UV-Vis spectroscopies and magnetic measurements and the three selected complexes were studied using thermal analysis. The crystal structure of [(Cu( (en)
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