About: Syntheses and study on nickel nad copper complexes with 1,3,5-benzenetricarboxylic acid. Crystal and molecular structure of [Cu3(mdpta)3(btc)](ClO4)3.4H2O     Goto   Sponge   NotDistinct   Permalink

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  • Nickel and copper complexes containing 1,3,5-benzenetricarboxylic acid, with a combination of selected N-donor ligands and Schiff bases, of the composition Ni3(bimz)6(btc)2.12H2O (1), Ni3(btz)9(btc)2.12H2O (2), Ni2(L1)(btc).7H2O (3), Ni3(L2)2(Hbtc).9H2O (4), Ni2(L3)(btc).4H2O (5), Cu2(L4)(tc).7H2O (6), [Cu3(pmdien)3(btc)](ClO4)3.6H2O (7) and [Cu3(mdpta)3(btc)](ClO4)3.4H2O (8); H3btc = 1,3,5-benzenetricarboxylic acid, bimz = benzimidazole, btz = benztriazole, L1 = 2-[(phenylimino)methyl]phenol, L2 = N,N'-bis(salicylidene)propylenediamine, L3 = 2-[(2-nitrophenyl)methylene]phenol, L4 = 2-[(4-methoxy-phenylimino)methyl]phenol, pmdien = N,N,N',N'', N''-pentamethyldiethylenetriamine, mdpta = N,N-bis(3-aminopropyl)methylamine, have been synthesized. The crystal and molecular structure of complex 8 was solved. The complex is trinuclear with btc3- bridge.
  • Nickel and copper complexes containing 1,3,5-benzenetricarboxylic acid, with a combination of selected N-donor ligands and Schiff bases, of the composition Ni3(bimz)6(btc)2.12H2O (1), Ni3(btz)9(btc)2.12H2O (2), Ni2(L1)(btc).7H2O (3), Ni3(L2)2(Hbtc).9H2O (4), Ni2(L3)(btc).4H2O (5), Cu2(L4)(tc).7H2O (6), [Cu3(pmdien)3(btc)](ClO4)3.6H2O (7) and [Cu3(mdpta)3(btc)](ClO4)3.4H2O (8); H3btc = 1,3,5-benzenetricarboxylic acid, bimz = benzimidazole, btz = benztriazole, L1 = 2-[(phenylimino)methyl]phenol, L2 = N,N'-bis(salicylidene)propylenediamine, L3 = 2-[(2-nitrophenyl)methylene]phenol, L4 = 2-[(4-methoxy-phenylimino)methyl]phenol, pmdien = N,N,N',N'', N''-pentamethyldiethylenetriamine, mdpta = N,N-bis(3-aminopropyl)methylamine, have been synthesized. The crystal and molecular structure of complex 8 was solved. The complex is trinuclear with btc3- bridge. (en)
Title
  • Syntheses and study on nickel nad copper complexes with 1,3,5-benzenetricarboxylic acid. Crystal and molecular structure of [Cu3(mdpta)3(btc)](ClO4)3.4H2O
  • Syntheses and study on nickel nad copper complexes with 1,3,5-benzenetricarboxylic acid. Crystal and molecular structure of [Cu3(mdpta)3(btc)](ClO4)3.4H2O (en)
skos:prefLabel
  • Syntheses and study on nickel nad copper complexes with 1,3,5-benzenetricarboxylic acid. Crystal and molecular structure of [Cu3(mdpta)3(btc)](ClO4)3.4H2O
  • Syntheses and study on nickel nad copper complexes with 1,3,5-benzenetricarboxylic acid. Crystal and molecular structure of [Cu3(mdpta)3(btc)](ClO4)3.4H2O (en)
skos:notation
  • RIV/61989592:15310/07:00009829!RIV10-MSM-15310___
http://linked.open...avai/riv/aktivita
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  • S
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  • 3
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  • 453868
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  • RIV/61989592:15310/07:00009829
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  • nickel(II); copper(II); 1,3,-benzenetricarboxylic (trimesic) acid; X-ray structure; magnetic properties (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [2AFEE2409F6D]
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  • Polyhedron
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  • 26
http://linked.open...iv/tvurceVysledku
  • Petříček, Václav
  • Kameníček, Jiří
  • Kopel, Pavel
  • Kalińska, Božena
  • Kurečka, Aleš
  • Mroziński, Jerzy
issn
  • 0277-5387
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  • 15310
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