Description
| - Nickel and copper complexes containing 1,3,5-benzenetricarboxylic acid, with a combination of selected N-donor ligands and Schiff bases, of the composition Ni3(bimz)6(btc)2.12H2O (1), Ni3(btz)9(btc)2.12H2O (2), Ni2(L1)(btc).7H2O (3), Ni3(L2)2(Hbtc).9H2O (4), Ni2(L3)(btc).4H2O (5), Cu2(L4)(tc).7H2O (6), [Cu3(pmdien)3(btc)](ClO4)3.6H2O (7) and [Cu3(mdpta)3(btc)](ClO4)3.4H2O (8); H3btc = 1,3,5-benzenetricarboxylic acid, bimz = benzimidazole, btz = benztriazole, L1 = 2-[(phenylimino)methyl]phenol, L2 = N,N'-bis(salicylidene)propylenediamine, L3 = 2-[(2-nitrophenyl)methylene]phenol, L4 = 2-[(4-methoxy-phenylimino)methyl]phenol, pmdien = N,N,N',N'', N''-pentamethyldiethylenetriamine, mdpta = N,N-bis(3-aminopropyl)methylamine, have been synthesized. The crystal and molecular structure of complex 8 was solved. The complex is trinuclear with btc3- bridge.
- Nickel and copper complexes containing 1,3,5-benzenetricarboxylic acid, with a combination of selected N-donor ligands and Schiff bases, of the composition Ni3(bimz)6(btc)2.12H2O (1), Ni3(btz)9(btc)2.12H2O (2), Ni2(L1)(btc).7H2O (3), Ni3(L2)2(Hbtc).9H2O (4), Ni2(L3)(btc).4H2O (5), Cu2(L4)(tc).7H2O (6), [Cu3(pmdien)3(btc)](ClO4)3.6H2O (7) and [Cu3(mdpta)3(btc)](ClO4)3.4H2O (8); H3btc = 1,3,5-benzenetricarboxylic acid, bimz = benzimidazole, btz = benztriazole, L1 = 2-[(phenylimino)methyl]phenol, L2 = N,N'-bis(salicylidene)propylenediamine, L3 = 2-[(2-nitrophenyl)methylene]phenol, L4 = 2-[(4-methoxy-phenylimino)methyl]phenol, pmdien = N,N,N',N'', N''-pentamethyldiethylenetriamine, mdpta = N,N-bis(3-aminopropyl)methylamine, have been synthesized. The crystal and molecular structure of complex 8 was solved. The complex is trinuclear with btc3- bridge. (en)
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