About: Tris(chloristane)(mi(3)-Trithiocyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N',N'',N''-pentamethyldiethylenetriamine-kappa N-3,N',N'')copper(II)]tris(perchlorate)

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About: Tris(chloristane)(mi(3)-Trithiocyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N',N'',N''-pentamethyldiethylenetriamine-kappa N-3,N',N'')copper(II)]tris(perchlorate) Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	V uvedené sloučenině, [Cu-3(C9H23N3)(3)(C3N3S3)](ClO4)(3), tři atomy Cu(II) jsou můstkovány trithiokyanurátovým(3-) aniontem (ttc), každý centrální atom je v deformovaném trigonálně - bipyramidálním uspořádání koordinován třemi atomy z tridentátního ligandu N,N,N',N'',N''-pentamethyldiethylentriaminu a jedním atomem síry a jedním atomem dusíku z ligandu ttc. Sekundární struktura je stabilizována pomocí slabých vodíkových vazeb typu C-H...O, které spojují kation a chloristanové anionty. (cs) In the title compound, [Cu-3(C9H23N3)(3)(C3N3S3)](ClO4)(3), the three Cu-II centres, related by the body-diagonal threefold rotation symmetry along [111], are bridged by a trithiocyanurate(3-) anion (ttc), with each centre having a considerably distorted trigonal - bipyramidal geometry and bonded to three N atoms of a tridentate N,N,N',N'',N''-pentamethyldiethylenetriamine ligand, and one S and N atoms of the ttc ligand. The secondary structure is estabilized by a variety of weak hydrogen bonds of the type C-H...O connecting the cation and perchlorate anions. In the title compound, [Cu-3(C9H23N3)(3)(C3N3S3)](ClO4)(3), the three Cu-II centres, related by the body-diagonal threefold rotation symmetry along [111], are bridged by a trithiocyanurate(3-) anion (ttc), with each centre having a considerably distorted trigonal - bipyramidal geometry and bonded to three N atoms of a tridentate N,N,N',N'',N''-pentamethyldiethylenetriamine ligand, and one S and N atoms of the ttc ligand. The secondary structure is estabilized by a variety of weak hydrogen bonds of the type C-H...O connecting the cation and perchlorate anions. (en)
Title	Tris(chloristane)(mi(3)-Trithiocyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N',N'',N''-pentamethyldiethylenetriamine-kappa N-3,N',N'')copper(II)]tris(perchlorate) Tris(chloristane)(mi(3)-Trithiocyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N',N'',N''-pentamethyldiethylenetriamine-kappa N-3,N',N'')copper(II)]tris(perchlorate) (en) Tris(chloristan)(mi(3)-trithiokyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N',N'',N''-pentamethyldiethylentriamin-kappa N-3,N',N'')měďnatý (cs)
skos:prefLabel	Tris(chloristane)(mi(3)-Trithiocyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N',N'',N''-pentamethyldiethylenetriamine-kappa N-3,N',N'')copper(II)]tris(perchlorate) Tris(chloristane)(mi(3)-Trithiocyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N',N'',N''-pentamethyldiethylenetriamine-kappa N-3,N',N'')copper(II)]tris(perchlorate) (en) Tris(chloristan)(mi(3)-trithiokyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N',N'',N''-pentamethyldiethylentriamin-kappa N-3,N',N'')měďnatý (cs)
skos:notation	RIV/61989592:15310/07:00004774!RIV08-MSM-15310___
http://linked.open.../vavai/riv/strany	m1742-m1743
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM6198959218)
http://linked.open...iv/cisloPeriodika	6
http://linked.open...vai/riv/dodaniDat	2008
http://linked.open...aciTvurceVysledku	Čermáková, Šárka Trávníček, Zdeněk Marek, Jaromír
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	455858
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/07:00004774
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	structure; copper(II); trithiocyanurato (en)
http://linked.open.../riv/klicoveSlovo	structure copper(II) trithiocyanurato
http://linked.open...odStatuVydavatele	DK - Dánské království
http://linked.open...ontrolniKodProRIV	[15EB15FDA253]
http://linked.open...i/riv/nazevZdroje	Acta Crystallographica Section E - Structure Reports Online
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...UplatneniVysledku	2007
http://linked.open...v/svazekPeriodika	63
http://linked.open...iv/tvurceVysledku	Marek, Jaromír Trávníček, Zdeněk Čermáková, Šárka
http://linked.open...n/vavai/riv/zamer	Komplexní sloučeniny a oxidy přechodných kovů s využitím v bioaplikacích a nanotechnologiích
issn	1600-5368
number of pages	2 (xsd:int)
http://localhost/t...ganizacniJednotka	15310
is http://linked.open...avai/riv/vysledek of	Tris(chloristane)(mi(3)-Trithiocyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N',N'',N''-pentamethyldiethylenetriamine-kappa N-3,N',N'')copper(II)]tris(perchlorate) Tris(chloristane)(mi(3)-Trithiocyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N',N'',N''-pentamethyldiethylenetriamine-kappa N-3,N',N'')copper(II)]tris(perchlorate) Tris(chloristane)(mi(3)-Trithiocyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N',N'',N''-pentamethyldiethylenetriamine-kappa N-3,N',N'')copper(II)]tris(perchlorate)

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