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  • Montmorillonite particles were modified by iron oxides using the precipitation process with the aim to monitor the differences in the structural and magnetic properties of intercalated and adsorbed Fe3+. The Mössbauer spectra recorded at 5 K in zero and 6 T external fields, IR spectra and TG curves measured in zero and 32 mT fields identified the ferrihydrite pillars in an interlayer space of the montmorillonite structure and γ-Fe2O3 nanoparticles adsorbed on the mineral surface. The temperature dependent Mössbauer spectra (25-300 K) reflect the superparamagnetic behaviour of maghemite nanoparticles and ferrihydrite pillars with the blocking temperatures of about 80 and 25 K, respectively.
  • Montmorillonite particles were modified by iron oxides using the precipitation process with the aim to monitor the differences in the structural and magnetic properties of intercalated and adsorbed Fe3+. The Mössbauer spectra recorded at 5 K in zero and 6 T external fields, IR spectra and TG curves measured in zero and 32 mT fields identified the ferrihydrite pillars in an interlayer space of the montmorillonite structure and γ-Fe2O3 nanoparticles adsorbed on the mineral surface. The temperature dependent Mössbauer spectra (25-300 K) reflect the superparamagnetic behaviour of maghemite nanoparticles and ferrihydrite pillars with the blocking temperatures of about 80 and 25 K, respectively. (en)
Title
  • Mössbauer study of iron oxide modified montmorillonite
  • Mössbauer study of iron oxide modified montmorillonite (en)
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  • Mössbauer study of iron oxide modified montmorillonite
  • Mössbauer study of iron oxide modified montmorillonite (en)
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  • RIV/61989592:15310/05:00003417!RIV10-MSM-15310___
http://linked.open...avai/riv/aktivita
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  • P(1M0512), Z(AV0Z20410507), Z(AV0Z30860518)
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  • 1-4
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  • 531254
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  • RIV/61989592:15310/05:00003417
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  • Mössbauer effect - iron oxide - montmorillonite (en)
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  • NL - Nizozemsko
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  • [56DD4182E696]
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  • Hyperfine Interactions
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http://linked.open...v/svazekPeriodika
  • 165
http://linked.open...iv/tvurceVysledku
  • Bartoňková, Helena
  • Pechoušek, Jiří
  • Schneeweiss, Oldřich
  • Zbořil, Radek
  • Martinec, Petr
  • Mašláň, Miroslav
http://linked.open...n/vavai/riv/zamer
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  • 0304-3843
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  • 15310
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