About: Nickel(II) Dithiocarbamates with AsI3 and SbI3 as Mixed Ligands

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Nikelnaté dithikarbamáty s AsI3 a SbI3 jako směsnými ligandy byly charakterizovány elementární, termickou, rentgenovou, spektroskopickou, magnetochemickou a konduktometrickou analýzou. (cs) Ni(II) dithiocarbamates with AsI3 and SbI3 as ligands of the composition [Ni(hmidtc)2(AsI3)] (1), [Ni(bzbutdtc)2(AsI3)] (2), [Ni(bzbutdtc)2(SbI3)].2CHCl3 (3), [Ni(bz2dtc)2(AsI3)] (4), [Ni(bz2dtc)(SbI3)].CS2 (5), [Ni(bz2dtc)2(AsI3)2].CHCl3 (6), [Ni(hmidtc)2(SbI3)2] (7) and [Ni(cetdtc)2(AsI3)2] (8), (hmidtc = hexamethyleneiminedithiocarbamate, bzbutdtc = benzylbutyldithiocarbamate, bz2dtc = dibenzyldithiocarbamate, cetdtc = cyclohexylethyldithiocarbamate, dtc = S2CN-) have been synthesized. The complexes have been characterized by elemental analysis, thermal analysis, IR and UV/VIS spectroscopies, magnetochemical and conductivity measurements as square-pyramidal (1-5) and octahedral (6-8) complexes. X-ray analysis of [Ni(bz2dtc)2(AsI3)] and [Ni(bz2dtc)2(SbI3)].CS2 confirmed square-pyramidal arrangement around nickel in both complexes with the NiS4As and NiS4Sb chromophore, respectively. Ni(II) dithiocarbamates with AsI3 and SbI3 as ligands of the composition [Ni(hmidtc)2(AsI3)] (1), [Ni(bzbutdtc)2(AsI3)] (2), [Ni(bzbutdtc)2(SbI3)].2CHCl3 (3), [Ni(bz2dtc)2(AsI3)] (4), [Ni(bz2dtc)(SbI3)].CS2 (5), [Ni(bz2dtc)2(AsI3)2].CHCl3 (6), [Ni(hmidtc)2(SbI3)2] (7) and [Ni(cetdtc)2(AsI3)2] (8), (hmidtc = hexamethyleneiminedithiocarbamate, bzbutdtc = benzylbutyldithiocarbamate, bz2dtc = dibenzyldithiocarbamate, cetdtc = cyclohexylethyldithiocarbamate, dtc = S2CN-) have been synthesized. The complexes have been characterized by elemental analysis, thermal analysis, IR and UV/VIS spectroscopies, magnetochemical and conductivity measurements as square-pyramidal (1-5) and octahedral (6-8) complexes. X-ray analysis of [Ni(bz2dtc)2(AsI3)] and [Ni(bz2dtc)2(SbI3)].CS2 confirmed square-pyramidal arrangement around nickel in both complexes with the NiS4As and NiS4Sb chromophore, respectively. (en)
Title	Nickel(II) Dithiocarbamates with AsI3 and SbI3 as Mixed Ligands Nikelnaté dithikarbamáty s AsI3 a SbI3 jako směsnými ligandy (cs) Nickel(II) Dithiocarbamates with AsI3 and SbI3 as Mixed Ligands (en)
skos:prefLabel	Nickel(II) Dithiocarbamates with AsI3 and SbI3 as Mixed Ligands Nikelnaté dithikarbamáty s AsI3 a SbI3 jako směsnými ligandy (cs) Nickel(II) Dithiocarbamates with AsI3 and SbI3 as Mixed Ligands (en)
skos:notation	RIV/61989592:15310/05:00001857!RIV06-MSM-15310___
http://linked.open.../vavai/riv/strany	637-644
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/02/0436), Z(MSM6198959218)
http://linked.open...iv/cisloPeriodika	4
http://linked.open...vai/riv/dodaniDat	2006
http://linked.open...aciTvurceVysledku	Husárek, Josef Pavlíček, Marek Trávníček, Zdeněk Pastorek, Richard Kameníček, Jiří Šindelář, Zdeněk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	532855
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/05:00001857
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Nickel(II); dithiocarbamate; AsI3; SbI3; synthesis; X-ray structures (en)
http://linked.open.../riv/klicoveSlovo	Nickel(II) synthesis X-ray structures dithiocarbamate AsI3 SbI3
http://linked.open...odStatuVydavatele	PL - Polská republika
http://linked.open...ontrolniKodProRIV	[7D1C212F9201]
http://linked.open...i/riv/nazevZdroje	Polish Journal of Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	6 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Application of Crystallographic Databases in Scientific Practice
http://linked.open...UplatneniVysledku	2005
http://linked.open...v/svazekPeriodika	79
http://linked.open...iv/tvurceVysledku	Cvek, Boris Trávníček, Zdeněk Pastorek, Richard Kameníček, Jiří Šindelář, Zdeněk Pavlíček, Marek Husárek, Josef
http://linked.open...n/vavai/riv/zamer	Komplexní sloučeniny a oxidy přechodných kovů s využitím v bioaplikacích a nanotechnologiích
issn	0137-5083
number of pages	8 (xsd:int)
http://localhost/t...ganizacniJednotka	15310
is http://linked.open...avai/riv/vysledek of	Nickel(II) Dithiocarbamates with AsI3 and SbI3 as Mixed Ligands

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