About: Oxalato complexes of copper(II) with chelating diamines. Crystal structure of [Cu(dmen)ox(H2O)](2)[Cu(dmen)(2)](ClO4)(2)

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About: Oxalato complexes of copper(II) with chelating diamines. Crystal structure of [Cu(dmen)ox(H2O)](2)[Cu(dmen)(2)](ClO4)(2) Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Four new oxalato complexes of copper(II) of composition [Cu(dmen)ox(H2O)](2) [Cu(dmen)(2)](ClO4)(2) (1) (dmen = N,N-dimethylethylenediamine, H(2)ox =oxalic acid), [(Cu(dmen)H2O)(2)Ox](ClO4)(2) . H2O (2), [Cu(tmen)(H2O)(ox)Cu(aep)(H2O)](ClO4)(2) (3) (tmen= N,N,N',N'-tetramethylethylenediamine, aep = 2-(2-aminoethyl)pyridine) and [(Cu(dben)NO3)(2)ox] (4) (dben = N,N'-dibenzylethylenediamine) have been prepared and characterised by IR and UV-Vis spectroscopies and magnetic measurements. The crystal struct ure of [Cu(dmen)ox(H2O)](2)[Cu(dmen)(2)](ClO4)(2) (1) has been determined by single-crystal X-ray analysis. The structure of 1 contains a neutral [Cu(dmen)ox(H2O)] complex, a cationic [Cu(dmen)(2)](2+) complex and perchlorate anions. The copper(II) atom of the neutral [Cu(dmen)ox(H2O)] unit possesses a distorted square-pyramidal environment with two oxygen atoms of oxalate and two nitrogen atoms of dmen in the basal plane and an oxygen atom of a water molecule in the apical position. The copper(II) atom Four new oxalato complexes of copper(II) of composition [Cu(dmen)ox(H2O)](2) [Cu(dmen)(2)](ClO4)(2) (1) (dmen = N,N-dimethylethylenediamine, H(2)ox =oxalic acid), [(Cu(dmen)H2O)(2)Ox](ClO4)(2) . H2O (2), [Cu(tmen)(H2O)(ox)Cu(aep)(H2O)](ClO4)(2) (3) (tmen= N,N,N',N'-tetramethylethylenediamine, aep = 2-(2-aminoethyl)pyridine) and [(Cu(dben)NO3)(2)ox] (4) (dben = N,N'-dibenzylethylenediamine) have been prepared and characterised by IR and UV-Vis spectroscopies and magnetic measurements. The crystal struct ure of [Cu(dmen)ox(H2O)](2)[Cu(dmen)(2)](ClO4)(2) (1) has been determined by single-crystal X-ray analysis. The structure of 1 contains a neutral [Cu(dmen)ox(H2O)] complex, a cationic [Cu(dmen)(2)](2+) complex and perchlorate anions. The copper(II) atom of the neutral [Cu(dmen)ox(H2O)] unit possesses a distorted square-pyramidal environment with two oxygen atoms of oxalate and two nitrogen atoms of dmen in the basal plane and an oxygen atom of a water molecule in the apical position. The copper(II) atom (en)
Title	Oxalato complexes of copper(II) with chelating diamines. Crystal structure of [Cu(dmen)ox(H2O)](2)[Cu(dmen)(2)](ClO4)(2) Oxalato complexes of copper(II) with chelating diamines. Crystal structure of [Cu(dmen)ox(H2O)](2)[Cu(dmen)(2)](ClO4)(2) (en)
skos:prefLabel	Oxalato complexes of copper(II) with chelating diamines. Crystal structure of [Cu(dmen)ox(H2O)](2)[Cu(dmen)(2)](ClO4)(2) Oxalato complexes of copper(II) with chelating diamines. Crystal structure of [Cu(dmen)ox(H2O)](2)[Cu(dmen)(2)](ClO4)(2) (en)
skos:notation	RIV/61989592:15310/02:00001647!RIV/2003/MSM/153103/N
http://linked.open.../vavai/riv/strany	1203-1209
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM 153100007)
http://linked.open...iv/cisloPeriodika	12-13
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Smékal, Zdeněk Kameníček, Jiří Šindelář, Zdeněk Kopel, Pavel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	657634
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/02:00001647
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	copper(II) complexes; oxalato complexes; oxalato-bridged complexes; magnetic properties; crystal structures (en)
http://linked.open.../riv/klicoveSlovo	oxalato complexes crystal structures magnetic properties oxalato-bridged complexes copper(II) complexes
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[68B51680DE31]
http://linked.open...i/riv/nazevZdroje	Polyhedron
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...UplatneniVysledku	2002
http://linked.open...v/svazekPeriodika	21
http://linked.open...iv/tvurceVysledku	Smékal, Zdeněk Kameníček, Jiří Kopel, Pavel Žák, Zdirad Šindelář, Zdeněk Klasová, Pavla Wrzeszcz, Grzegorz
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20153100007
issn	0277-5387
number of pages	7 (xsd:int)
http://localhost/t...ganizacniJednotka	15310

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