About: Synthesis, crystal structure and magnetic properties of novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN)-Cu(ept)](n)center dot 4nH(2)O (ept = N-(2-aminoethyl)propane-1,3-diamine)

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About: Synthesis, crystal structure and magnetic properties of novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN)-Cu(ept)](n)center dot 4nH(2)O (ept = N-(2-aminoethyl)propane-1,3-diamine) Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN) Cu(ept)](n)(.)4nH(2)O (ept = N-(2-aminoethyl)-propane-1,3 diamine) was obtained by the reaction of Cu(ClO4)(2)(.)6H(2)O with N-(2-aminoethyl)propane-1,3-diamine and Na 2[Fe(CN)(5)NO](.)2H(2)O in water. This compound was characterized by IR, UV-VIS and EPR spectroscopies and magnetic measurement. Single-crystal X-ray structure analysis revealed that the title complex has a one-dimensional polymeric structure containing hexacoordinate iron(II) with five cyanide ligands (two of them, in trans position, bridging) and one nitrosyl group, and pentacoordinate copper(II) with N-(2 aminoethyl)propane-1,3-diamine and two sites occupied by bridging cyanide ligands. Magnetic investigation revealed a very weak anti ferromagnetic interaction between the copper atoms (superexchange interaction parameter J = -1.7(1) cm(-1); H = -JS(i)S(i+1)) within the chain through the diamagnetic [Fe(CN)(5)NO](2-) ions. The novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN) Cu(ept)](n)(.)4nH(2)O (ept = N-(2-aminoethyl)-propane-1,3 diamine) was obtained by the reaction of Cu(ClO4)(2)(.)6H(2)O with N-(2-aminoethyl)propane-1,3-diamine and Na 2[Fe(CN)(5)NO](.)2H(2)O in water. This compound was characterized by IR, UV-VIS and EPR spectroscopies and magnetic measurement. Single-crystal X-ray structure analysis revealed that the title complex has a one-dimensional polymeric structure containing hexacoordinate iron(II) with five cyanide ligands (two of them, in trans position, bridging) and one nitrosyl group, and pentacoordinate copper(II) with N-(2 aminoethyl)propane-1,3-diamine and two sites occupied by bridging cyanide ligands. Magnetic investigation revealed a very weak anti ferromagnetic interaction between the copper atoms (superexchange interaction parameter J = -1.7(1) cm(-1); H = -JS(i)S(i+1)) within the chain through the diamagnetic [Fe(CN)(5)NO](2-) ions. (en)
Title	Synthesis, crystal structure and magnetic properties of novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN)-Cu(ept)](n)center dot 4nH(2)O (ept = N-(2-aminoethyl)propane-1,3-diamine) Synthesis, crystal structure and magnetic properties of novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN)-Cu(ept)](n)center dot 4nH(2)O (ept = N-(2-aminoethyl)propane-1,3-diamine) (en)
skos:prefLabel	Synthesis, crystal structure and magnetic properties of novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN)-Cu(ept)](n)center dot 4nH(2)O (ept = N-(2-aminoethyl)propane-1,3-diamine) Synthesis, crystal structure and magnetic properties of novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN)-Cu(ept)](n)center dot 4nH(2)O (ept = N-(2-aminoethyl)propane-1,3-diamine) (en)
skos:notation	RIV/61989592:15310/01:00001648!RIV/2003/MSM/153103/N
http://linked.open.../vavai/riv/strany	1490-1498
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM 153100007)
http://linked.open...iv/cisloPeriodika	10
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Smékal, Zdeněk Kameníček, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	698113
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/01:00001648
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	copper(II); iron(II); cyanide-bridged complexes; diamines; nitroprussides; cyanides; magnetic properties; crystal structure (en)
http://linked.open.../riv/klicoveSlovo	diamines iron(II) crystal structure magnetic properties cyanide-bridged complexes nitroprussides cyanides copper(II)
http://linked.open...odStatuVydavatele	CZ - Česká republika
http://linked.open...ontrolniKodProRIV	[4CC4BE564613]
http://linked.open...i/riv/nazevZdroje	Collection of Czechoslovak Chemical Communications
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...UplatneniVysledku	2001
http://linked.open...v/svazekPeriodika	66
http://linked.open...iv/tvurceVysledku	Smékal, Zdeněk Svoboda, Ingrid Kameníček, Jiří Escuer, Albert
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20153100007
issn	0010-0765
number of pages	9 (xsd:int)
http://localhost/t...ganizacniJednotka	15310

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