About: High electrical anisotropy in hydrochloric acid doped polyaniline/phyllosilicate nanocomposites; Effect of phyllosilicate matrix, synthesis pathway and pressure     Goto   Sponge   NotDistinct   Permalink

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Description
  • Pressed tablets from polyaniline/phyllosilicate nanocomposites have been prepared under various conditions in order to optimize anisotropic conductivity of composite by ordering of flat phyllosilicate particles intercalated with polyaniline (PANI). Powder samples of PANI/phyllosilicate nanocomposites have been prepared using two phyllosilicates, montmorillonite and vermiculite, with a different layer charge. Two precursors were used, anilinium hydrochloride and anilinium sulfate. Prepared PANI/phyllosilicate composites were subsequently doped by hydrochloric acid via rinsing after polymerization process and for the DC conductivity measurements pressed into tablets. Applied pressure was 28 MPa and 128 MPa. Highly anisotropic conductivity has been achieved in pressed tablets. The in-plane conductivity for PANI/montmorillonite was 0.084 S/cm, i.e. 1000 times higher than in the direction perpendicular to the tablet plane. Increase of pressure up to 128 MPa led to dramatic decrease of conductivity.
  • Pressed tablets from polyaniline/phyllosilicate nanocomposites have been prepared under various conditions in order to optimize anisotropic conductivity of composite by ordering of flat phyllosilicate particles intercalated with polyaniline (PANI). Powder samples of PANI/phyllosilicate nanocomposites have been prepared using two phyllosilicates, montmorillonite and vermiculite, with a different layer charge. Two precursors were used, anilinium hydrochloride and anilinium sulfate. Prepared PANI/phyllosilicate composites were subsequently doped by hydrochloric acid via rinsing after polymerization process and for the DC conductivity measurements pressed into tablets. Applied pressure was 28 MPa and 128 MPa. Highly anisotropic conductivity has been achieved in pressed tablets. The in-plane conductivity for PANI/montmorillonite was 0.084 S/cm, i.e. 1000 times higher than in the direction perpendicular to the tablet plane. Increase of pressure up to 128 MPa led to dramatic decrease of conductivity. (en)
Title
  • High electrical anisotropy in hydrochloric acid doped polyaniline/phyllosilicate nanocomposites; Effect of phyllosilicate matrix, synthesis pathway and pressure
  • High electrical anisotropy in hydrochloric acid doped polyaniline/phyllosilicate nanocomposites; Effect of phyllosilicate matrix, synthesis pathway and pressure (en)
skos:prefLabel
  • High electrical anisotropy in hydrochloric acid doped polyaniline/phyllosilicate nanocomposites; Effect of phyllosilicate matrix, synthesis pathway and pressure
  • High electrical anisotropy in hydrochloric acid doped polyaniline/phyllosilicate nanocomposites; Effect of phyllosilicate matrix, synthesis pathway and pressure (en)
skos:notation
  • RIV/61989100:27640/13:86086148!RIV14-GA0-27640___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(EE.2.3.20.0074), P(GAP108/11/1057)
http://linked.open...iv/cisloPeriodika
  • srpen 2013
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 77333
http://linked.open...ai/riv/idVysledku
  • RIV/61989100:27640/13:86086148
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • conductivity; anisotropy; pressed tablet; nanocomposite; polyaniline; phyllosilicate (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [99FDDEE2AD8C]
http://linked.open...i/riv/nazevZdroje
  • Applied Clay Science
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 80-81
http://linked.open...iv/tvurceVysledku
  • Matějka, Vlastimil
  • Stýskala, Vítězslav
  • Čapková, Pavla
  • Neuwirthová, Lucie
  • Mamulová Kutláková, Kateřina
  • Tokarský, Jonáš
  • Kulhánková, Lenka
http://linked.open...ain/vavai/riv/wos
  • 000325039100017
issn
  • 0169-1317
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.clay.2013.06.029
http://localhost/t...ganizacniJednotka
  • 27640
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