About: Clay-Supported 2-Phenyl-1H-Imidazole Derivatives for Heterogeneous Catalysis of Henry Reaction     Goto   Sponge   NotDistinct   Permalink

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Description
  • Six derivatives (1-6) of 2-phenyl-1H-imidazole were tested as catalysts of Henry reaction. Three new (4-6) 2-phenyl-1H-imidazole derivatives, differently substituted (thio)ureas, were synthesized and determined by 1H NMR and IR spectroscopy and elemental analysis. Two types of catalysis, homogeneous and heterogeneous, were examined and compared. Clay minerals Ca-MMT and Cu-MMT were used as solid supports for heterogeneous catalysis. The best results were obtained using compound 2 under conditions of heterogeneous method from the point of view of yield and reaction time.
  • Six derivatives (1-6) of 2-phenyl-1H-imidazole were tested as catalysts of Henry reaction. Three new (4-6) 2-phenyl-1H-imidazole derivatives, differently substituted (thio)ureas, were synthesized and determined by 1H NMR and IR spectroscopy and elemental analysis. Two types of catalysis, homogeneous and heterogeneous, were examined and compared. Clay minerals Ca-MMT and Cu-MMT were used as solid supports for heterogeneous catalysis. The best results were obtained using compound 2 under conditions of heterogeneous method from the point of view of yield and reaction time. (en)
Title
  • Clay-Supported 2-Phenyl-1H-Imidazole Derivatives for Heterogeneous Catalysis of Henry Reaction
  • Clay-Supported 2-Phenyl-1H-Imidazole Derivatives for Heterogeneous Catalysis of Henry Reaction (en)
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  • Clay-Supported 2-Phenyl-1H-Imidazole Derivatives for Heterogeneous Catalysis of Henry Reaction
  • Clay-Supported 2-Phenyl-1H-Imidazole Derivatives for Heterogeneous Catalysis of Henry Reaction (en)
skos:notation
  • RIV/61989100:27640/11:86085773!RIV13-MSM-27640___
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  • I, P(GA205/08/0869), Z(MSM0021627501), Z(MSM6198910016)
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  • 4
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  • 190546
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  • RIV/61989100:27640/11:86085773
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  • histidine; ligands; complexes; nitroaldol reaction; asymmetric catalysis; Imidazole derivatives (en)
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  • US - Spojené státy americké
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  • [3BAA2C69F444]
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  • Journal of Heterocyclic Chemistry
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  • 48
http://linked.open...iv/tvurceVysledku
  • Holešová, Sylva
  • Ludwig, Miroslav
  • Pařík, Patrik
http://linked.open...ain/vavai/riv/wos
  • 000293745900027
http://linked.open...n/vavai/riv/zamer
issn
  • 0022-152X
number of pages
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  • 10.1002/jhet.669
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  • 27640
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