About: Hexacyanochromates(III) and Hexacyanocobaltates(III) of Copper(II) with Tridentate and Tetradentate N-donor Ligands. Crystal Structure of [{Cu(ept)}3{Co(CN)6}2] H2O (ept = N-(2-aminoethyl)-1,3-propandiamine)

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About: Hexacyanochromates(III) and Hexacyanocobaltates(III) of Copper(II) with Tridentate and Tetradentate N-donor Ligands. Crystal Structure of [{Cu(ept)}3{Co(CN)6}2] H2O (ept = N-(2-aminoethyl)-1,3-propandiamine) Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The following complexes [{Cu(ept)}3{Cr(CN)6}2] 5H2O, [{Cu(hatce)}3{Cr(CN)6}2] 15H2O, [{Cu(hatco)}3{Cr(CN)6}2] 14H2O, [{Cu(ept)}3{Co(CN)6}2] 5H2O, [{Cu(hatce)}3{Co(CN)6}2] 18H2O and [{Cu(medpt)}3{Co(CN)6}2] H2O (ept = N-(2-aminoethyl)-1,3-propandiamine, hatce = 1,3,6,10,12,15-hexaazatricyclo[13.3.1.16,10]eicosane, hatco = 1,3,6,9,11,14-hexaazatricyclo[12.2.1.16,9]octadecane and medpt = N,N-bis-(3-aminopropyl)methylamine) have been synthesized by the reactions of Cu(ClO4)2 6H2O or Cu(NO3)2 3H2O and ept or medpt, or [Cu(hatce)](ClO4)2 2H2O and [Cu(hatco)Cl]ClO4 H2O, and K3[Cr(CN)6] or K3[Co(CN)6] in aqueous solution, respectively. All the compounds have been characterized by elemental analyses, IR and UV-Vis spectroscopies and magnetic measurements and the three selected complexes were studied using thermal analysis. The crystal structure of [{Cu(ept)}3{Co(CN)6}2] H2O has been determined by single-crystal X-ray analysis - the studied compound can be formulated as [{Cu(ept)}6{Co(CN)6}3][Co(CN)6] 2H2O. T The following complexes [{Cu(ept)}3{Cr(CN)6}2] 5H2O, [{Cu(hatce)}3{Cr(CN)6}2] 15H2O, [{Cu(hatco)}3{Cr(CN)6}2] 14H2O, [{Cu(ept)}3{Co(CN)6}2] 5H2O, [{Cu(hatce)}3{Co(CN)6}2] 18H2O and [{Cu(medpt)}3{Co(CN)6}2] H2O (ept = N-(2-aminoethyl)-1,3-propandiamine, hatce = 1,3,6,10,12,15-hexaazatricyclo[13.3.1.16,10]eicosane, hatco = 1,3,6,9,11,14-hexaazatricyclo[12.2.1.16,9]octadecane and medpt = N,N-bis-(3-aminopropyl)methylamine) have been synthesized by the reactions of Cu(ClO4)2 6H2O or Cu(NO3)2 3H2O and ept or medpt, or [Cu(hatce)](ClO4)2 2H2O and [Cu(hatco)Cl]ClO4 H2O, and K3[Cr(CN)6] or K3[Co(CN)6] in aqueous solution, respectively. All the compounds have been characterized by elemental analyses, IR and UV-Vis spectroscopies and magnetic measurements and the three selected complexes were studied using thermal analysis. The crystal structure of [{Cu(ept)}3{Co(CN)6}2] H2O has been determined by single-crystal X-ray analysis - the studied compound can be formulated as [{Cu(ept)}6{Co(CN)6}3][Co(CN)6] 2H2O. T (en)
Title	Hexacyanochromates(III) and Hexacyanocobaltates(III) of Copper(II) with Tridentate and Tetradentate N-donor Ligands. Crystal Structure of [{Cu(ept)}3{Co(CN)6}2] H2O (ept = N-(2-aminoethyl)-1,3-propandiamine) Hexacyanochromates(III) and Hexacyanocobaltates(III) of Copper(II) with Tridentate and Tetradentate N-donor Ligands. Crystal Structure of [{Cu(ept)}3{Co(CN)6}2] H2O (ept = N-(2-aminoethyl)-1,3-propandiamine) (en)
skos:prefLabel	Hexacyanochromates(III) and Hexacyanocobaltates(III) of Copper(II) with Tridentate and Tetradentate N-donor Ligands. Crystal Structure of [{Cu(ept)}3{Co(CN)6}2] H2O (ept = N-(2-aminoethyl)-1,3-propandiamine) Hexacyanochromates(III) and Hexacyanocobaltates(III) of Copper(II) with Tridentate and Tetradentate N-donor Ligands. Crystal Structure of [{Cu(ept)}3{Co(CN)6}2] H2O (ept = N-(2-aminoethyl)-1,3-propandiamine) (en)
skos:notation	RIV/61989100:27640/09:00021842!RIV10-GA0-27640___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA205/08/0869), Z(MSM6198910016)
http://linked.open...iv/cisloPeriodika	10
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Mamulová Kutláková, Kateřina
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola báňská - Technická univerzita Ostrava / Centrum nanotechnologií
http://linked.open...dnocenehoVysledku	317061
http://linked.open...ai/riv/idVysledku	RIV/61989100:27640/09:00021842
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	copper(II); cobalt(III); chromium(III); cyano-bridged complexes; structure (en)
http://linked.open.../riv/klicoveSlovo	structure copper(II) chromium(III) cobalt(III) cyano-bridged complexes
http://linked.open...odStatuVydavatele	PL - Polská republika
http://linked.open...ontrolniKodProRIV	[0C6B0FECC640]
http://linked.open...i/riv/nazevZdroje	Pol.Journal Chem.
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Clay minerals as host matrices for functional nanostructures
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	83
http://linked.open...iv/tvurceVysledku	Smékal, Zdeněk Mamulová Kutláková, Kateřina Šindelář, Zdeněk Neels, Antonia
http://linked.open...n/vavai/riv/zamer	Syntéza, struktura a vlastnosti nanomateriálů založených na bázi interkalovaných fylosylikátů
issn	0137-5083
number of pages	10 (xsd:int)
http://localhost/t...ganizacniJednotka	27640
is http://linked.open...avai/riv/vysledek of	Hexacyanochromates(III) and Hexacyanocobaltates(III) of Copper(II) with Tridentate and Tetradentate N-donor Ligands. Crystal Structure of [{Cu(ept)}3{Co(CN)6}2] H2O (ept = N-(2-aminoethyl)-1,3-propandiamine)

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