About: One-dimensional complex {[Cu(medpt)][Ag(CN)2]2}n     Goto   Sponge   NotDistinct   Permalink

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Description
  • The novel compound, {[Cu(medpt)][Ag(CN)2]2}n (medpt = N,N-bis-(3-aminopropyl)methylamine), was isolated from a reaction mixture containing Cu(ClO4)2 6H2O, medpt and K[Ag(CN)2]. The new complex was characterized by IR spectroscopy, magnetochemical studies and by X-ray single crystal diffraction. The structure contains [Cu(medpt)]2+ units being bridged by [Ag(CN)2]- units resulting in chains of the composition [-CN-Cu(medpt)-NC-Ag-]n, and dicyanoargentate anions. Ag-Ag interactions link free [Ag(CN)2]- anions to the chain. The copper(II) atom is five coordinated to two cyanide-nitrogen and three medpt-nitrogen atoms in a distorted square-pyramidal arrangement.
  • The novel compound, {[Cu(medpt)][Ag(CN)2]2}n (medpt = N,N-bis-(3-aminopropyl)methylamine), was isolated from a reaction mixture containing Cu(ClO4)2 6H2O, medpt and K[Ag(CN)2]. The new complex was characterized by IR spectroscopy, magnetochemical studies and by X-ray single crystal diffraction. The structure contains [Cu(medpt)]2+ units being bridged by [Ag(CN)2]- units resulting in chains of the composition [-CN-Cu(medpt)-NC-Ag-]n, and dicyanoargentate anions. Ag-Ag interactions link free [Ag(CN)2]- anions to the chain. The copper(II) atom is five coordinated to two cyanide-nitrogen and three medpt-nitrogen atoms in a distorted square-pyramidal arrangement. (en)
Title
  • One-dimensional complex {[Cu(medpt)][Ag(CN)2]2}n
  • One-dimensional complex {[Cu(medpt)][Ag(CN)2]2}n (en)
skos:prefLabel
  • One-dimensional complex {[Cu(medpt)][Ag(CN)2]2}n
  • One-dimensional complex {[Cu(medpt)][Ag(CN)2]2}n (en)
skos:notation
  • RIV/61989100:27640/09:00021841!RIV10-GA0-27640___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA205/08/0869), Z(MSM6198910016)
http://linked.open...iv/cisloPeriodika
  • 2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 331653
http://linked.open...ai/riv/idVysledku
  • RIV/61989100:27640/09:00021841
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • copper(II) complexes; dicyanoargentates(I); cyano-bridged complexes; X-ray structure analysis (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • SK - Slovenská republika
http://linked.open...ontrolniKodProRIV
  • [8B40FFF5B1E1]
http://linked.open...i/riv/nazevZdroje
  • Acta Chimica Slovenica
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 56
http://linked.open...iv/tvurceVysledku
  • Smékal, Zdeněk
  • Mamulová Kutláková, Kateřina
  • Neels, Antonia
http://linked.open...n/vavai/riv/zamer
issn
  • 1318-0207
number of pages
http://localhost/t...ganizacniJednotka
  • 27640
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