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Description
| - The novel compound, {[Cu(medpt)][Ag(CN)2]2}n (medpt = N,N-bis-(3-aminopropyl)methylamine), was isolated from a reaction mixture containing Cu(ClO4)2 6H2O, medpt and K[Ag(CN)2]. The new complex was characterized by IR spectroscopy, magnetochemical studies and by X-ray single crystal diffraction. The structure contains [Cu(medpt)]2+ units being bridged by [Ag(CN)2]- units resulting in chains of the composition [-CN-Cu(medpt)-NC-Ag-]n, and dicyanoargentate anions. Ag-Ag interactions link free [Ag(CN)2]- anions to the chain. The copper(II) atom is five coordinated to two cyanide-nitrogen and three medpt-nitrogen atoms in a distorted square-pyramidal arrangement.
- The novel compound, {[Cu(medpt)][Ag(CN)2]2}n (medpt = N,N-bis-(3-aminopropyl)methylamine), was isolated from a reaction mixture containing Cu(ClO4)2 6H2O, medpt and K[Ag(CN)2]. The new complex was characterized by IR spectroscopy, magnetochemical studies and by X-ray single crystal diffraction. The structure contains [Cu(medpt)]2+ units being bridged by [Ag(CN)2]- units resulting in chains of the composition [-CN-Cu(medpt)-NC-Ag-]n, and dicyanoargentate anions. Ag-Ag interactions link free [Ag(CN)2]- anions to the chain. The copper(II) atom is five coordinated to two cyanide-nitrogen and three medpt-nitrogen atoms in a distorted square-pyramidal arrangement. (en)
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Title
| - One-dimensional complex {[Cu(medpt)][Ag(CN)2]2}n
- One-dimensional complex {[Cu(medpt)][Ag(CN)2]2}n (en)
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skos:prefLabel
| - One-dimensional complex {[Cu(medpt)][Ag(CN)2]2}n
- One-dimensional complex {[Cu(medpt)][Ag(CN)2]2}n (en)
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skos:notation
| - RIV/61989100:27640/09:00021841!RIV10-GA0-27640___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA205/08/0869), Z(MSM6198910016)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61989100:27640/09:00021841
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - copper(II) complexes; dicyanoargentates(I); cyano-bridged complexes; X-ray structure analysis (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Smékal, Zdeněk
- Mamulová Kutláková, Kateřina
- Neels, Antonia
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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is http://linked.open...avai/riv/vysledek
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