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  • Vermiculite (VER)was exfoliated to be used as organovermiculite nanofiller (ODA/VER) for polypropylene (PP)/ VER nanocomposites.We used three procedures. P1: low-temperature intercalation of melted octadecylamine (ODA) led to the regular bilayer arrangement of organic molecules in the interlayer space. P2: mechanical exfoliation of ODA/VER by jet milling decreased the crystallite size. P3: chemical exfoliation using an oxidizing agent potassium persulfate and subsequent intercalation with ODA created a mixture of monolayer and bilayer arrangements of organic cations in the interlayer. The thermal compounding of the organovermiculites (4 wt.%) with maleated PP at 30 and 50 rpm caused the partial deintercalation of the organovermiculite and organovermiculite pretreated with the oxidizing agent. The jet milled ODA/VERwas very well dispersed within PP matrix. Thermal stability of PP and PP/VER nanocomposites with differently exfoliated ODA/VER nanofillers was evaluated by thermogravimetric analysis.
  • Vermiculite (VER)was exfoliated to be used as organovermiculite nanofiller (ODA/VER) for polypropylene (PP)/ VER nanocomposites.We used three procedures. P1: low-temperature intercalation of melted octadecylamine (ODA) led to the regular bilayer arrangement of organic molecules in the interlayer space. P2: mechanical exfoliation of ODA/VER by jet milling decreased the crystallite size. P3: chemical exfoliation using an oxidizing agent potassium persulfate and subsequent intercalation with ODA created a mixture of monolayer and bilayer arrangements of organic cations in the interlayer. The thermal compounding of the organovermiculites (4 wt.%) with maleated PP at 30 and 50 rpm caused the partial deintercalation of the organovermiculite and organovermiculite pretreated with the oxidizing agent. The jet milled ODA/VERwas very well dispersed within PP matrix. Thermal stability of PP and PP/VER nanocomposites with differently exfoliated ODA/VER nanofillers was evaluated by thermogravimetric analysis. (en)
Title
  • Organovermiculite nanofillers in polypropylene
  • Organovermiculite nanofillers in polypropylene (en)
skos:prefLabel
  • Organovermiculite nanofillers in polypropylene
  • Organovermiculite nanofillers in polypropylene (en)
skos:notation
  • RIV/61989100:27640/09:00021835!RIV10-GA0-27640___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA205/05/2548), P(GA205/08/0869), Z(AV0Z30860518), Z(MSM6198910016)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 332132
http://linked.open...ai/riv/idVysledku
  • RIV/61989100:27640/09:00021835
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Organovermiculite; nanofiller; exfoliation; X-ray powder diffraction; jet milling; thermal stability (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [FED7EA10F77C]
http://linked.open...i/riv/nazevZdroje
  • Applied Clay Science
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 43
http://linked.open...iv/tvurceVysledku
  • Matějka, Vlastimil
  • Plevová, Eva
  • Simha Martynková, Gražyna
  • Valášková, Marta
  • Barabaszová, Karla
  • Měřínská, D.
http://linked.open...n/vavai/riv/zamer
issn
  • 0169-1317
number of pages
http://localhost/t...ganizacniJednotka
  • 27640
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