About: Kinetic studies of graphon and coal char reaction with NO and O2: Direct non-linear regression from TG curves.     Goto   Sponge   NotDistinct   Permalink

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  • The reactions of carbonaceous materials (graphon and coal-char) with NO, O2 and NO+O2 were investigated by a thermogravimetric analysis (TGA). A method of direct non-linear regression of the kinetic equation was applied for a simultaneous calculation of the apparent activation energy, frequency factor and reaction order from a single TG curve of carbon gasification in various atmospheres. It was proven that the proposed calculation method is applicable for the calculation of kinetic parameters from overlapping processes. Calculations from TG curves of the above reactions demonstrate that NO-carbon and (NO+O2)-carbon reactions contain two processes, while O2-carbon is a single process. The reaction order of O2-carbon is approximate 0.5, while the reaction orders of NO-carbon or (NO+O2)-carbon reaction are dependent on the process and type of carbon. Graphon shows higher apparent activation energy than coal-char due to the pore structure and uncatalysed effects.
  • The reactions of carbonaceous materials (graphon and coal-char) with NO, O2 and NO+O2 were investigated by a thermogravimetric analysis (TGA). A method of direct non-linear regression of the kinetic equation was applied for a simultaneous calculation of the apparent activation energy, frequency factor and reaction order from a single TG curve of carbon gasification in various atmospheres. It was proven that the proposed calculation method is applicable for the calculation of kinetic parameters from overlapping processes. Calculations from TG curves of the above reactions demonstrate that NO-carbon and (NO+O2)-carbon reactions contain two processes, while O2-carbon is a single process. The reaction order of O2-carbon is approximate 0.5, while the reaction orders of NO-carbon or (NO+O2)-carbon reaction are dependent on the process and type of carbon. Graphon shows higher apparent activation energy than coal-char due to the pore structure and uncatalysed effects. (en)
  • The reactions of carbonaceous materials (graphon and coal-char) with NO, O2 and NO+O2 were investigated by a thermogravimetric analysis (TGA). A method of direct non-linear regression of the kinetic equation was applied for a simultaneous calculation of the apparent activation energy, frequency factor and reaction order from a single TG curve of carbon gasification in various atmospheres. It was proven that the proposed calculation method is applicable for the calculation of kinetic parameters from overlapping processes. Calculations from TG curves of the above reactions demonstrate that NO-carbon and (NO+O2)-carbon reactions contain two processes, while O2-carbon is a single process. The reaction order of O2-carbon is approximate 0.5, while the reaction orders of NO-carbon or (NO+O2)-carbon reaction are dependent on the process and type of carbon. Graphon shows higher apparent activation energy than coal-char due to the pore structure and uncatalysed effects. (cs)
Title
  • Kinetic studies of graphon and coal char reaction with NO and O2: Direct non-linear regression from TG curves.
  • Kinetika reakce grafitu a koksu s NO a O2 (cs)
  • Kinetic studies of graphon and coal char reaction with NO and O2: Direct non-linear regression from TG curves. (en)
skos:prefLabel
  • Kinetic studies of graphon and coal char reaction with NO and O2: Direct non-linear regression from TG curves.
  • Kinetika reakce grafitu a koksu s NO a O2 (cs)
  • Kinetic studies of graphon and coal char reaction with NO and O2: Direct non-linear regression from TG curves. (en)
skos:notation
  • RIV/61988987:17310/05:00000017!RIV07-GA0-17310___
http://linked.open.../vavai/riv/strany
  • 651
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA105/03/0538)
http://linked.open...iv/cisloPeriodika
  • 0
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 526737
http://linked.open...ai/riv/idVysledku
  • RIV/61988987:17310/05:00000017
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • TGA; kinetics; NO reduction; coal combustion; non-linear regresion (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [4714C93949D9]
http://linked.open...i/riv/nazevZdroje
  • Fuel Processing Technology
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 86
http://linked.open...iv/tvurceVysledku
  • Slovák, Václav
  • Haynes, B. S.
  • Wang, Shaobin
issn
  • 0378-3820
number of pages
http://localhost/t...ganizacniJednotka
  • 17310
is http://linked.open...avai/riv/vysledek of
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