About: Novel iron complexes bearing N6-substituted adenosine derivatives: Synthesis, magnetic, Fe-57 Mossbauer, DFT, and in vitro cytotoxicity studies     Goto   Sponge   NotDistinct   Permalink

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  • Iron complexes (1-7) involving N6-benzyladenosine derivatives of the predominant composition [Fe(L-n)Cl-3]center dot H2O {where L-1 = N6-(2-fluorobenzyl)adenosine (1), L-2 = N6-(4-fluorobenzyl)adenosine (2), L-3 = N6-(2-trifluoromethylbenzyl)adenosine (3), L-4 = N6-(3-trifluoromethylbenzyl)adenosine (4), L-5 = N6-(4-trifluoromethylbenzyl)adenosine (5), L-6 = N6-(4-trifluoromethoxybenzyl)adenosine (6), and L-7 = N6-(4-chlorobenzyl)adenosine (7)} have been synthesized. The compounds have been characterized by elemental analysis, variable-temperature and in-field Fe-57 Mossbauer, ES+ MS, FTIR, H-1 and C-13 NMR spectroscopies, magnetochemical and conductivity measurements, thermal (TGA/DSC/DTA) analyses, and DFT calculations. It has been found that the organic molecule is coordinated to iron via N7 atom of the appropriate adenosine derivative and the products are represented by mixtures of complexes with various iron oxidation (Fe-III/Fe-II) and spin states (S = 5/2, 4/2, 3/2, 2/2) and geometries (tetr...
  • Iron complexes (1-7) involving N6-benzyladenosine derivatives of the predominant composition [Fe(L-n)Cl-3]center dot H2O {where L-1 = N6-(2-fluorobenzyl)adenosine (1), L-2 = N6-(4-fluorobenzyl)adenosine (2), L-3 = N6-(2-trifluoromethylbenzyl)adenosine (3), L-4 = N6-(3-trifluoromethylbenzyl)adenosine (4), L-5 = N6-(4-trifluoromethylbenzyl)adenosine (5), L-6 = N6-(4-trifluoromethoxybenzyl)adenosine (6), and L-7 = N6-(4-chlorobenzyl)adenosine (7)} have been synthesized. The compounds have been characterized by elemental analysis, variable-temperature and in-field Fe-57 Mossbauer, ES+ MS, FTIR, H-1 and C-13 NMR spectroscopies, magnetochemical and conductivity measurements, thermal (TGA/DSC/DTA) analyses, and DFT calculations. It has been found that the organic molecule is coordinated to iron via N7 atom of the appropriate adenosine derivative and the products are represented by mixtures of complexes with various iron oxidation (Fe-III/Fe-II) and spin states (S = 5/2, 4/2, 3/2, 2/2) and geometries (tetr... (en)
  • Novel iron complexes bearing N6-substituted adenosine derivatives: Synthesis, magnetic, Fe-57 Mossbauer, DFT, and in vitro cytotoxicity studies. (cs)
Title
  • Novel iron complexes bearing N6-substituted adenosine derivatives: Synthesis, magnetic, Fe-57 Mossbauer, DFT, and in vitro cytotoxicity studies
  • Novel iron complexes bearing N6-substituted adenosine derivatives: Synthesis, magnetic, Fe-57 Mossbauer, DFT, and in vitro cytotoxicity studies (en)
  • Novel iron complexes bearing N6-substituted adenosine derivatives: Synthesis, magnetic, Fe-57 Mossbauer, DFT, and in vitro cytotoxicity studies (cs)
skos:prefLabel
  • Novel iron complexes bearing N6-substituted adenosine derivatives: Synthesis, magnetic, Fe-57 Mossbauer, DFT, and in vitro cytotoxicity studies
  • Novel iron complexes bearing N6-substituted adenosine derivatives: Synthesis, magnetic, Fe-57 Mossbauer, DFT, and in vitro cytotoxicity studies (en)
  • Novel iron complexes bearing N6-substituted adenosine derivatives: Synthesis, magnetic, Fe-57 Mossbauer, DFT, and in vitro cytotoxicity studies (cs)
skos:notation
  • RIV/61389030:_____/08:00325895!RIV09-AV0-61389030
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z50380511)
http://linked.open...iv/cisloPeriodika
  • 18
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 383270
http://linked.open...ai/riv/idVysledku
  • RIV/61389030:_____/08:00325895
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • iron complexes; adenosine derivatives; Fe-57 Mossbauer spectroscopy (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [A990BE918FEE]
http://linked.open...i/riv/nazevZdroje
  • Bioorganic & Medicinal Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 16
http://linked.open...iv/tvurceVysledku
  • Trávníček, Zdeněk
  • Popa, Igor
  • Čajan, Michal
  • Zbořil, R.
  • Mikulík, J.
http://linked.open...ain/vavai/riv/wos
  • 000259173400046
http://linked.open...n/vavai/riv/zamer
issn
  • 0968-0896
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