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| Description
| - Mixed-ligand trinuclear Cu(II) complex involving trithiocyanurate(3-) anion (ttc(3-)) and N,N,N',N%22,N%22-pentamethyidiethylenetriamine (pmdien) in the coordination sphere of composition [Cu-3(pmdien)(3)(mu-ttc)](ClO4)(3) has been prepared. The complex has been characterized by EA, IR, UV-Vis, and mass spectroscopy. We can assume, that the complex is trinuclear with central atoms connected by trithiocyanurate(3-) bridges. Each central atom is in deformed trigonal bypiramidal arrangement formed by chelating S,N atoms of ttc(3-) and by three N atoms of pmdien. Temperature dependence of magnetic susceptibility and EPR spectroscopy have also been employed to characterize the compound. Magnetic susceptibility measurements over the 1.8-300 K temperature range revealed antiferromagnetic interactions among central atoms. The antitumor activity in vitro against G-361 (human malignant melanoma), HOS (human osteogenic sarcoma), K-562 (human chronic myelogenous leukaemia) and MCF-7 (human breast adenocarcinoma) t...
- Mixed-ligand trinuclear Cu(II) complex involving trithiocyanurate(3-) anion (ttc(3-)) and N,N,N',N%22,N%22-pentamethyidiethylenetriamine (pmdien) in the coordination sphere of composition [Cu-3(pmdien)(3)(mu-ttc)](ClO4)(3) has been prepared. The complex has been characterized by EA, IR, UV-Vis, and mass spectroscopy. We can assume, that the complex is trinuclear with central atoms connected by trithiocyanurate(3-) bridges. Each central atom is in deformed trigonal bypiramidal arrangement formed by chelating S,N atoms of ttc(3-) and by three N atoms of pmdien. Temperature dependence of magnetic susceptibility and EPR spectroscopy have also been employed to characterize the compound. Magnetic susceptibility measurements over the 1.8-300 K temperature range revealed antiferromagnetic interactions among central atoms. The antitumor activity in vitro against G-361 (human malignant melanoma), HOS (human osteogenic sarcoma), K-562 (human chronic myelogenous leukaemia) and MCF-7 (human breast adenocarcinoma) t... (en)
- Byl připraven směsný trojjaderný Cu(II) komplex obsahující v koordinační sféře trithiokyanurátový (3-) anion (ttc-3) a N,N,N',N', N''-pentamethyldiethylentriamin (pmdien), složení [Cu3(pmdien) 3(μ-tcc)](ClO4)3. Komplex byl charakterizován elementární analýzou, IČ, UV-Vis a hmotnostní spektrometrií. Můžeme předpokládat, že komplex je trojjaderný s centrálními atomy spojenými trithiokyanurátovými (3-) můstky. Všechny centrální atomy jsou v uspořádání deformované trizonální bypiramidy, chelatované S,N atomy z ttc(3-) a třemi N atomy pmdienu. Teplotní závislost magnetické susceptibility a EPR spektroskopie byly také využity k charakterizaci sloučeniny. Měření magnetické susceptibility v teplotním intervalu 1.8-300 K odhalilo antiferromagnetické interakce mezi centrálními atomy. Byla testována protinádorová aktivita in vitro na G-361 (lidský maligní melanom), HOS (liský kostní sarkom), K-562 (lidská chronická mielogenní leukémie), MCF-7 (lidský prsní adenokarcinom) nádorových buněčných liniích ale boh... (cs)
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| Title
| - Synthesis and properties of a trinuclear copper(II) complex with trithiocyanurate bridge
- Synthesis and properties of a trinuclear copper(II) complex with trithiocyanurate bridge (en)
- Syntéza a vlastnosti trinukleárního měďnatého komplexu s trithiokyanurátovým můstkem (cs)
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| skos:prefLabel
| - Synthesis and properties of a trinuclear copper(II) complex with trithiocyanurate bridge
- Synthesis and properties of a trinuclear copper(II) complex with trithiocyanurate bridge (en)
- Syntéza a vlastnosti trinukleárního měďnatého komplexu s trithiokyanurátovým můstkem (cs)
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| skos:notation
| - RIV/61389030:_____/07:00318752!RIV09-AV0-61389030
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
| - Z(AV0Z50380511), Z(MSM6198959218)
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
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| http://linked.open...ai/riv/idVysledku
| - RIV/61389030:_____/07:00318752
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| http://linked.open...riv/jazykVysledku
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| http://linked.open.../riv/klicovaSlova
| - copper(II); trithiocyanuric acid complexes; magnetic properties (en)
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| http://linked.open.../riv/klicoveSlovo
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| http://linked.open...odStatuVydavatele
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| http://linked.open...ontrolniKodProRIV
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| http://linked.open...i/riv/nazevZdroje
| - Polish Journal of Chemistry
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| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
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| http://linked.open...cetTvurcuVysledku
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| http://linked.open...UplatneniVysledku
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| http://linked.open...v/svazekPeriodika
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| http://linked.open...iv/tvurceVysledku
| - Doležal, Karel
- Bieńko, A.
- Kopel, P.
- Čermáková, Š.
- Kalińska, B.
- Mroziński, J.
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| http://linked.open...ain/vavai/riv/wos
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| http://linked.open...n/vavai/riv/zamer
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| issn
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| number of pages
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| is http://linked.open...avai/riv/vysledek
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