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Description
| - Polybenz-3,1-oxazinone-4 (PBOZ) fi lms are prepared via the thermal rearrangement of poly[(methylene- bis -anthranilamide) 4,4-diphenyloxidicarboxylic acid] (PAA) films by heating to 300 °C. PAA is synthesized by low-temperature polycondensation. The PBOZ fi lm exhibits excellent mechanical properties and a high glass-transition temperature. Conversion of PAA to PBOZ leads to an increase in the fractional free volume as a result of thermal dehydration and cyclization during membrane formation and due to the removal of residual solvent. The excess free volume in the PBOZ film is approximately 3–4% of the total volume. The gas permeability and selectivity of the PBOZ film is higher than that of the PAA film. The thermal rearrangement of polymers is recognized as a suitable method to improve separation efficiency.
- Polybenz-3,1-oxazinone-4 (PBOZ) fi lms are prepared via the thermal rearrangement of poly[(methylene- bis -anthranilamide) 4,4-diphenyloxidicarboxylic acid] (PAA) films by heating to 300 °C. PAA is synthesized by low-temperature polycondensation. The PBOZ fi lm exhibits excellent mechanical properties and a high glass-transition temperature. Conversion of PAA to PBOZ leads to an increase in the fractional free volume as a result of thermal dehydration and cyclization during membrane formation and due to the removal of residual solvent. The excess free volume in the PBOZ film is approximately 3–4% of the total volume. The gas permeability and selectivity of the PBOZ film is higher than that of the PAA film. The thermal rearrangement of polymers is recognized as a suitable method to improve separation efficiency. (en)
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Title
| - Synthesis and characterization of polybenzoxazinone and its prepolymer using gas separation
- Synthesis and characterization of polybenzoxazinone and its prepolymer using gas separation (en)
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skos:prefLabel
| - Synthesis and characterization of polybenzoxazinone and its prepolymer using gas separation
- Synthesis and characterization of polybenzoxazinone and its prepolymer using gas separation (en)
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skos:notation
| - RIV/61389013:_____/13:00421782!RIV14-GA0-61389013
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http://linked.open...avai/predkladatel
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61389013:_____/13:00421782
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - gas separation; polybenzoxazinone; polymer membranes (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - DE - Spolková republika Německo
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Macromolecular Chemistry and Physics
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Brožová, Libuše
- Pientka, Zbyněk
- Polotskaya, G. A.
- Gofman, I. V.
- Goikhman, M. Y.
- Podeshvo, I. V.
- Pulyalina, A. Y.
- Saprykina, N. N.
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
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