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  • Polybenz-3,1-oxazinone-4 (PBOZ) fi lms are prepared via the thermal rearrangement of poly[(methylene- bis -anthranilamide) 4,4-diphenyloxidicarboxylic acid] (PAA) films by heating to 300 °C. PAA is synthesized by low-temperature polycondensation. The PBOZ fi lm exhibits excellent mechanical properties and a high glass-transition temperature. Conversion of PAA to PBOZ leads to an increase in the fractional free volume as a result of thermal dehydration and cyclization during membrane formation and due to the removal of residual solvent. The excess free volume in the PBOZ film is approximately 3–4% of the total volume. The gas permeability and selectivity of the PBOZ film is higher than that of the PAA film. The thermal rearrangement of polymers is recognized as a suitable method to improve separation efficiency.
  • Polybenz-3,1-oxazinone-4 (PBOZ) fi lms are prepared via the thermal rearrangement of poly[(methylene- bis -anthranilamide) 4,4-diphenyloxidicarboxylic acid] (PAA) films by heating to 300 °C. PAA is synthesized by low-temperature polycondensation. The PBOZ fi lm exhibits excellent mechanical properties and a high glass-transition temperature. Conversion of PAA to PBOZ leads to an increase in the fractional free volume as a result of thermal dehydration and cyclization during membrane formation and due to the removal of residual solvent. The excess free volume in the PBOZ film is approximately 3–4% of the total volume. The gas permeability and selectivity of the PBOZ film is higher than that of the PAA film. The thermal rearrangement of polymers is recognized as a suitable method to improve separation efficiency. (en)
Title
  • Synthesis and characterization of polybenzoxazinone and its prepolymer using gas separation
  • Synthesis and characterization of polybenzoxazinone and its prepolymer using gas separation (en)
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  • Synthesis and characterization of polybenzoxazinone and its prepolymer using gas separation
  • Synthesis and characterization of polybenzoxazinone and its prepolymer using gas separation (en)
skos:notation
  • RIV/61389013:_____/13:00421782!RIV14-GA0-61389013
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  • I, P(GA104/09/1165)
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  • 24
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  • 109472
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  • RIV/61389013:_____/13:00421782
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  • gas separation; polybenzoxazinone; polymer membranes (en)
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  • DE - Spolková republika Německo
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  • [AD59575F8B67]
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  • Macromolecular Chemistry and Physics
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  • 214
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  • Brožová, Libuše
  • Pientka, Zbyněk
  • Polotskaya, G. A.
  • Gofman, I. V.
  • Goikhman, M. Y.
  • Podeshvo, I. V.
  • Pulyalina, A. Y.
  • Saprykina, N. N.
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  • 000329021400011
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  • 1022-1352
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  • 10.1002/macp.201300436
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