About: Modeling of interface mobility in the description of flow-induced coalescence in immiscible polymer blends     Goto   Sponge   NotDistinct   Permalink

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Description
  • A new semiempirical equation has been proposed for the rate of approach of highly flattened droplets, applicable in the whole range of the ratios, p, of viscosity of the dispersed droplets and matrix. The equation is utilized to calculate the probability, P c, that the droplet collision induced by shear or extensional flow is followed by the droplet fusion for systems with Newtonian droplets and Newtonian or viscoelastic matrix. The comparison of the results of these calculations with available experimental data and with the calculation using the trajectory analysis shows that the proposed model of the matrix drainage provides more reasonable results than the broadly applied model of partially mobile interface.
  • A new semiempirical equation has been proposed for the rate of approach of highly flattened droplets, applicable in the whole range of the ratios, p, of viscosity of the dispersed droplets and matrix. The equation is utilized to calculate the probability, P c, that the droplet collision induced by shear or extensional flow is followed by the droplet fusion for systems with Newtonian droplets and Newtonian or viscoelastic matrix. The comparison of the results of these calculations with available experimental data and with the calculation using the trajectory analysis shows that the proposed model of the matrix drainage provides more reasonable results than the broadly applied model of partially mobile interface. (en)
Title
  • Modeling of interface mobility in the description of flow-induced coalescence in immiscible polymer blends
  • Modeling of interface mobility in the description of flow-induced coalescence in immiscible polymer blends (en)
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  • Modeling of interface mobility in the description of flow-induced coalescence in immiscible polymer blends
  • Modeling of interface mobility in the description of flow-induced coalescence in immiscible polymer blends (en)
skos:notation
  • RIV/61389013:_____/13:00394378!RIV14-GA0-61389013
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  • I, P(GAP106/11/1069)
http://linked.open...iv/cisloPeriodika
  • 8
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  • 88873
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  • RIV/61389013:_____/13:00394378
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  • flow-induced coalescence; polymer blends; matrix drainage (en)
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  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [E23D423A5F93]
http://linked.open...i/riv/nazevZdroje
  • Colloid and Polymer Science
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  • 291
http://linked.open...iv/tvurceVysledku
  • Fortelný, Ivan
  • Jůza, Josef
http://linked.open...ain/vavai/riv/wos
  • 000322455100008
issn
  • 0303-402X
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s00396-013-2917-x
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