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  • Coalescence in molten quiescent polymer blends induced by van der Waals forces is studied theoretically. Interaction between a droplet and its nearest neighbor keeping spherical shape during drainage of the matrix trapped between them is considered. It is assumed that droplets having a time dependent radius R are randomly distributed in the blend through the whole course of the coalescence. Various approaches to calculation of the average time of coalescence, tc are compared. Calculated dependence of R on the time of coalescence, t, is compared with experimental results for polypropylene/ethylene–propylene rubber (PP/EPR) blends. Experimental results show decreasing slope of R3 vs. t dependence, especially for a higher content of dispersed EPR. Theories using average h0 or direct averaging of tc predict somewhat smaller rate of coalescence than that experimentally determined for PP/EPR blends. Reasons of these differences are discussed
  • Coalescence in molten quiescent polymer blends induced by van der Waals forces is studied theoretically. Interaction between a droplet and its nearest neighbor keeping spherical shape during drainage of the matrix trapped between them is considered. It is assumed that droplets having a time dependent radius R are randomly distributed in the blend through the whole course of the coalescence. Various approaches to calculation of the average time of coalescence, tc are compared. Calculated dependence of R on the time of coalescence, t, is compared with experimental results for polypropylene/ethylene–propylene rubber (PP/EPR) blends. Experimental results show decreasing slope of R3 vs. t dependence, especially for a higher content of dispersed EPR. Theories using average h0 or direct averaging of tc predict somewhat smaller rate of coalescence than that experimentally determined for PP/EPR blends. Reasons of these differences are discussed (en)
Title
  • Coalescence in quiescent polymer blends with a high content of the dispersed phase
  • Coalescence in quiescent polymer blends with a high content of the dispersed phase (en)
skos:prefLabel
  • Coalescence in quiescent polymer blends with a high content of the dispersed phase
  • Coalescence in quiescent polymer blends with a high content of the dispersed phase (en)
skos:notation
  • RIV/61389013:_____/12:00377756!RIV13-AV0-61389013
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • P(IAA200500903), Z(AV0Z40500505)
http://linked.open...iv/cisloPeriodika
  • 7
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  • 127573
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  • RIV/61389013:_____/12:00377756
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  • polymer blends; coalescence; molecular forces (en)
http://linked.open.../riv/klicoveSlovo
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  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [CC365D4859E6]
http://linked.open...i/riv/nazevZdroje
  • European Polymer Journal
http://linked.open...in/vavai/riv/obor
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http://linked.open...v/svazekPeriodika
  • 48
http://linked.open...iv/tvurceVysledku
  • Dimzoski, Bojan
  • Fortelný, Ivan
  • Jůza, Josef
http://linked.open...ain/vavai/riv/wos
  • 000306681200010
http://linked.open...n/vavai/riv/zamer
issn
  • 0014-3057
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.eurpolymj.2012.04.017
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