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Description
| - Nanocomposites of epoxies with a novel filler, amino-functional butyltin oxide cage (stannoxane), were prepared and characterized. The nanofiller displays a promising antioxidizing effect, besides mechanical matrix reinforcement. The reinforcement can be assigned to physical interactions among the polymer bonded nanofiller. Moreover, the stannoxane cage undergoes a rearrangement to larger poly amino-functional nano-objects at higher temperatures, which highly reduces its extractability: it is practically not extractable from the nanocomposites in most cases. Only a few weight percent of stannoxane are needed to achieve an optimal anti-oxidizing effect. The nanocomposite synthesis, stannoxane reactivity and dispersion (morphology via TEM and SAXS), as well as the nanofiller effect on mechanical properties (DMTA) and on thermal stability are discussed. A brief comparison is drawn between the stannoxanes and the previously investigated POSS nanofiller.
- Nanocomposites of epoxies with a novel filler, amino-functional butyltin oxide cage (stannoxane), were prepared and characterized. The nanofiller displays a promising antioxidizing effect, besides mechanical matrix reinforcement. The reinforcement can be assigned to physical interactions among the polymer bonded nanofiller. Moreover, the stannoxane cage undergoes a rearrangement to larger poly amino-functional nano-objects at higher temperatures, which highly reduces its extractability: it is practically not extractable from the nanocomposites in most cases. Only a few weight percent of stannoxane are needed to achieve an optimal anti-oxidizing effect. The nanocomposite synthesis, stannoxane reactivity and dispersion (morphology via TEM and SAXS), as well as the nanofiller effect on mechanical properties (DMTA) and on thermal stability are discussed. A brief comparison is drawn between the stannoxanes and the previously investigated POSS nanofiller. (en)
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Title
| - Preparation of novel, nanocomposite stannoxane-based organic-inorganic epoxy polymers containing ionic bonds
- Preparation of novel, nanocomposite stannoxane-based organic-inorganic epoxy polymers containing ionic bonds (en)
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skos:prefLabel
| - Preparation of novel, nanocomposite stannoxane-based organic-inorganic epoxy polymers containing ionic bonds
- Preparation of novel, nanocomposite stannoxane-based organic-inorganic epoxy polymers containing ionic bonds (en)
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skos:notation
| - RIV/61389013:_____/12:00372985!RIV12-AV0-61389013
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http://linked.open...avai/predkladatel
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GAP108/11/2151), P(IAA400500701), Z(AV0Z40500505)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
| - Kovářová, Jana
- Špírková, Milena
- Starovoytova, Larisa
- Matějka, Libor
- Šlouf, Miroslav
- Pleštil, Josef
- Strachota, Adam
- Steinhart, Miloš
- Hromádková, Jiřina
- Strachota, Beata
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61389013:_____/12:00372985
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - stannoxane; organic-inorganic hybrid; epoxy (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Kovářová, Jana
- Matějka, Libor
- Starovoytova, Larisa
- Šlouf, Miroslav
- Špírková, Milena
- Pleštil, Josef
- Strachota, Adam
- Steinhart, Miloš
- Hromádková, Jiřina
- Ribot, F.
- Strachota, Beata
- Whelan, P.
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://bibframe.org/vocab/doi
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is http://linked.open...avai/riv/vysledek
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