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  • Anilinium 5-sulfosalicylate was prepared and characterized by elemental analysis, and FTIR and NMR spectroscopies. It was polymerized in an aqueous solution using ammonium peroxydisulfate as an oxidant. The precipitated polyaniline 5-sulfosalicylate exhibited high thermal stability and conductivity of 0.13 S cm(-1). Its mass-average molar mass and polydispersity index were determined by gel-permeation chromatography as 22,900 g mol(-1) and 2.7, respectively. Elemental analysis and FTIR spectroscopy study of polyaniline 5-sulfosalicylate revealed the doping level and the oxidation state between emeraldine and protoemeraldine salt while corresponding studies of the polyaniline base indicate a small extent of the covalent bonding of 5-sulfosalicylate anions to polyaniline chains.
  • Anilinium 5-sulfosalicylate was prepared and characterized by elemental analysis, and FTIR and NMR spectroscopies. It was polymerized in an aqueous solution using ammonium peroxydisulfate as an oxidant. The precipitated polyaniline 5-sulfosalicylate exhibited high thermal stability and conductivity of 0.13 S cm(-1). Its mass-average molar mass and polydispersity index were determined by gel-permeation chromatography as 22,900 g mol(-1) and 2.7, respectively. Elemental analysis and FTIR spectroscopy study of polyaniline 5-sulfosalicylate revealed the doping level and the oxidation state between emeraldine and protoemeraldine salt while corresponding studies of the polyaniline base indicate a small extent of the covalent bonding of 5-sulfosalicylate anions to polyaniline chains. (en)
Title
  • Oxidative polymerization of anilinium 5-sulfosalicylate with peroxydisulfate in water
  • Oxidative polymerization of anilinium 5-sulfosalicylate with peroxydisulfate in water (en)
skos:prefLabel
  • Oxidative polymerization of anilinium 5-sulfosalicylate with peroxydisulfate in water
  • Oxidative polymerization of anilinium 5-sulfosalicylate with peroxydisulfate in water (en)
skos:notation
  • RIV/61389013:_____/10:00346392!RIV11-AV0-61389013
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(IAA400500905), Z(AV0Z40500505)
http://linked.open...iv/cisloPeriodika
  • 6
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 277876
http://linked.open...ai/riv/idVysledku
  • RIV/61389013:_____/10:00346392
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http://linked.open.../riv/klicovaSlova
  • anilinium 5-sulfosalicylate; peroxydisulfate; oxidative polymerization (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • SK - Slovenská republika
http://linked.open...ontrolniKodProRIV
  • [13E4C899983C]
http://linked.open...i/riv/nazevZdroje
  • Chemical Papers
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http://linked.open...v/svazekPeriodika
  • 64
http://linked.open...iv/tvurceVysledku
  • Ciric-Marjanovic, G.
  • Holler, Petr
  • Juranic, I.
  • Marjanovic, B.
  • Mentus, S.
http://linked.open...ain/vavai/riv/wos
  • 000282128600012
http://linked.open...n/vavai/riv/zamer
issn
  • 0366-6352
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