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| rdf:type
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| Description
| - Studovali jsme krystalickou strukturu a C-H...O=C vodíkové vazby pomocí infračervené (IR) spektroskopie a širokoúhlového rentgenova rozptylu poly(3-hydroxyvalerátu) v porovnání s poly(3-hydroxybutyrátem). Zkoumali jsme vzdálenosti mezi skupinami C=O v jednom helixu a CH3 nebo CH2 skupinami v jiném helixu pomocí rentgenových krystalografických dat. Ukázalo se, že vzdálenost mezi C=O a CH3 skupinou PHV je delší než van der Waalsův poloměr (2.72 Å), zatímco vzdálenost mezi skupinou C=O a dvěma CH2 skupinami v hlavním a vedlejším řetězci PHV je významně kratší než van der Waalsův poloměr. (cs)
- We have investigated crystal structure and C-H...O=C hydrogen bonding by using infrared (IR) spectroscopy and wide-angle X-ray diffraction (WAXD) for poly(3-hydroxyvalerate) (PHV) in comparison with those of poly(3-hydroxybutyrate) (PHB). We have explored the distances between the C=O group in one helix and the CH3 or CH2 groups in the other helix of PHV by using X-ray crystallographic data. It has turned out that the distance between the C=O group and the CH3 group of PHV is longer than that of the van der Waals separation (2.72 Å), while the distance between the C=O group and the two CH2 groups in the main and side chains of PHV is significantly shorter than that of the van der Waals separation.
- We have investigated crystal structure and C-H...O=C hydrogen bonding by using infrared (IR) spectroscopy and wide-angle X-ray diffraction (WAXD) for poly(3-hydroxyvalerate) (PHV) in comparison with those of poly(3-hydroxybutyrate) (PHB). We have explored the distances between the C=O group in one helix and the CH3 or CH2 groups in the other helix of PHV by using X-ray crystallographic data. It has turned out that the distance between the C=O group and the CH3 group of PHV is longer than that of the van der Waals separation (2.72 Å), while the distance between the C=O group and the two CH2 groups in the main and side chains of PHV is significantly shorter than that of the van der Waals separation. (en)
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| Title
| - Crystal structures, thermal behaviors, and C-H...O=C hydrogen bondings of poly(3-hydroxyvalerate) and poly(3-hydroxybutyrate) studied by infrared spectroscopy and X-ray diffraction
- Krystalická struktura, teplotní chování a C-H...O=C vodíkové vazby poly(3-hydroxyvalerátu) a poly(3-hydroxybutyrátu) studované infračervenou spektroskopií a rentgenovou difrakcí (cs)
- Crystal structures, thermal behaviors, and C-H...O=C hydrogen bondings of poly(3-hydroxyvalerate) and poly(3-hydroxybutyrate) studied by infrared spectroscopy and X-ray diffraction (en)
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| skos:prefLabel
| - Crystal structures, thermal behaviors, and C-H...O=C hydrogen bondings of poly(3-hydroxyvalerate) and poly(3-hydroxybutyrate) studied by infrared spectroscopy and X-ray diffraction
- Krystalická struktura, teplotní chování a C-H...O=C vodíkové vazby poly(3-hydroxyvalerátu) a poly(3-hydroxybutyrátu) studované infračervenou spektroskopií a rentgenovou difrakcí (cs)
- Crystal structures, thermal behaviors, and C-H...O=C hydrogen bondings of poly(3-hydroxyvalerate) and poly(3-hydroxybutyrate) studied by infrared spectroscopy and X-ray diffraction (en)
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| skos:notation
| - RIV/61389013:_____/08:00309157!RIV09-AV0-61389013
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
| - P(GA203/05/0425), Z(AV0Z40500505)
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
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| http://linked.open...ai/riv/idVysledku
| - RIV/61389013:_____/08:00309157
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| http://linked.open...riv/jazykVysledku
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| http://linked.open.../riv/klicovaSlova
| - poly(3-hydroxyvalerate); poly(3-hydroxybutyrate); infrared spectroscopy (en)
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| http://linked.open.../riv/klicoveSlovo
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| http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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| http://linked.open...ontrolniKodProRIV
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| http://linked.open...i/riv/nazevZdroje
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| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
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| http://linked.open...cetTvurcuVysledku
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| http://linked.open...vavai/riv/projekt
| |
| http://linked.open...UplatneniVysledku
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| http://linked.open...v/svazekPeriodika
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| http://linked.open...iv/tvurceVysledku
| - Dybal, Jiří
- Ozaki, Y.
- Ando, Y.
- Iwata, T.
- Noda, I.
- Sato, H.
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| http://linked.open...ain/vavai/riv/wos
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| http://linked.open...n/vavai/riv/zamer
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| issn
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| number of pages
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| is http://linked.open...avai/riv/vysledek
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