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rdf:type
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Description
| - Pevná stříbrná amalgámová elektroda bez obsahu kapalné rtuti (p-AgSAE) se ukázala jako experimentálně vhodná, spolehlivá a environmentálně příznivá náhrada za visicí rtuťovou kapkovou elektrodu v elektrochemické analýze. Doposud byly většinou užívány pro stanovení některých anorganických iontů nebo nukleových bazí. Je popisována jejich úspěšná aplikace pro stanovení pěti biologicky významných organických látek: L-a-amino kyselina cystein (komplex s Cu+), kyselina askorbová, nitro sloučeniny (1,3-dinitrobenzen a 2,4-dinitrotoluen), a benzaldehyd. V některých případech elektroda vykazovala meze detekce na úrovni HMDE. Elektrochemická regenerace elektrodového povrchu umožnila dosažení nízkých hladin RSD (0.89-3.3%). (cs)
- Liquid-mercury free, polished silver solid amalgam electrode (p-AgSAE) proved experimentally to be a suitable, reliable and environmentally friendly substitute for the hanging mercury drop electrode in electrochemical analyses. It has been so far mostly used for determinations of some inorganic ions or some nucleic bases. Its successful applications for determination of five biologically important organic compounds are described: L-a-amino acid cysteine (complex with Cu+), ascorbic acid, nitro compounds (1,3-dinitrobenzene and 2,4-dinitrotoluene), and benzaldehyde. In some cases this electrode exhibits limits of detection as low as HMDE does. Electrochemical regenerations of electrode surface enabled achievement of low levels of RSD (0.89-3.3%).
- Liquid-mercury free, polished silver solid amalgam electrode (p-AgSAE) proved experimentally to be a suitable, reliable and environmentally friendly substitute for the hanging mercury drop electrode in electrochemical analyses. It has been so far mostly used for determinations of some inorganic ions or some nucleic bases. Its successful applications for determination of five biologically important organic compounds are described: L-a-amino acid cysteine (complex with Cu+), ascorbic acid, nitro compounds (1,3-dinitrobenzene and 2,4-dinitrotoluene), and benzaldehyde. In some cases this electrode exhibits limits of detection as low as HMDE does. Electrochemical regenerations of electrode surface enabled achievement of low levels of RSD (0.89-3.3%). (en)
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Title
| - Liquid-Mercury Free Silver Solid Amalgam Electrode - Tool for Electroanalysis of Organic Compounds
- Pevná stříbrná amalgámová elektroda bez obsahu kapalné rtuti - nástroj pro elektroanalýzu organických sloučenin (cs)
- Liquid-Mercury Free Silver Solid Amalgam Electrode - Tool for Electroanalysis of Organic Compounds (en)
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skos:prefLabel
| - Liquid-Mercury Free Silver Solid Amalgam Electrode - Tool for Electroanalysis of Organic Compounds
- Pevná stříbrná amalgámová elektroda bez obsahu kapalné rtuti - nástroj pro elektroanalýzu organických sloučenin (cs)
- Liquid-Mercury Free Silver Solid Amalgam Electrode - Tool for Electroanalysis of Organic Compounds (en)
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skos:notation
| - RIV/61389013:_____/07:00099787!RIV08-AV0-61389013
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA203/07/1195), P(LC06035), Z(AV0Z40400503), Z(AV0Z40500505)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61389013:_____/07:00099787
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - ascorbic acid; solid silver amalgam electrodes; cysteine; voltammetry (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Navrátil, Tomáš
- Vlček, Milan
- Šelešovská-Fadrná, R.
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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is http://linked.open...avai/riv/vysledek
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