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Description
  • Electrical properties of binary samples containing photoconducting poly[methyl(phenyl)silylene] with admixed photochromic spiropyran were investigated. A reversible chemical reaction of the photochromic system, driven by light and producing highly polar metastable species, manifests itself in a reversible modification of dark currents and photocurrents. The behaviour of the samples is explained assuming a reversible production and annihilation of dipolar traps associated with the polar molecules produced in the photochromic process. Use of similar materials as elements of molecular electroactive systems is postulated.
  • Electrical properties of binary samples containing photoconducting poly[methyl(phenyl)silylene] with admixed photochromic spiropyran were investigated. A reversible chemical reaction of the photochromic system, driven by light and producing highly polar metastable species, manifests itself in a reversible modification of dark currents and photocurrents. The behaviour of the samples is explained assuming a reversible production and annihilation of dipolar traps associated with the polar molecules produced in the photochromic process. Use of similar materials as elements of molecular electroactive systems is postulated. (en)
  • Byly studovány elektrické vlastnosti dvoukomponentních vzorků obsahujících fotovodivý poly[fenyl(methyl)silylen] s přísadou fotochromního spiropyranu. Reversibilní světlem řízená chemická reakce fotochromního systému, během které vznikají vysoce polární metastabilní produkty, indukuje vratné změny temnotního proudu a fotoproudu. Vysvětlení tohoto procesu je založeno na předpokladu vratného vzniku a zániku dipolárních pastí v závislosti na produkci polárních molekul vznikajících v průběhu fotochromního procesu. Je postulováno užití podobných materiálů pro přípravu molekulárních elektroaktivních prvků. (cs)
Title
  • A molecular device based on light controlled charge carrier mobility
  • Molekulární prvek založený na světlem řízené pohyblivosti nosičů náboje (cs)
  • A molecular device based on light controlled charge carrier mobility (en)
skos:prefLabel
  • A molecular device based on light controlled charge carrier mobility
  • Molekulární prvek založený na světlem řízené pohyblivosti nosičů náboje (cs)
  • A molecular device based on light controlled charge carrier mobility (en)
skos:notation
  • RIV/61389013:_____/04:00105696!RIV/2005/MSM/A55005/N
http://linked.open.../vavai/riv/strany
  • 395;402
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(OC D14.30), Z(AV0Z4050913), Z(MSM 113200001)
http://linked.open...iv/cisloPeriodika
  • 1-4
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 552985
http://linked.open...ai/riv/idVysledku
  • RIV/61389013:_____/04:00105696
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • electrical properties;photoconductivity;photochromism (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [6D836994C38D]
http://linked.open...i/riv/nazevZdroje
  • Applied Surface Science
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 234
http://linked.open...iv/tvurceVysledku
  • Nešpůrek, Stanislav
  • Sworakowski, J.
  • Weiter, M.
  • Wang, Geng
  • Combellas, C.
http://linked.open...n/vavai/riv/zamer
issn
  • 0169-4332
number of pages
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