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  • The preparation of Br-terminated methyl methacrylate macronitiator (MI) from living precursors obtained by anionic or GTP polymerization was examined. Tranformation of the precursor end groups with bromine or N-bromosuccinimide, resp., afforded 60 % functionalization. MI was utilized in the synthesis of ABC triblock copolymers by ATRP. Another macroinitiator, a monodisperse, in-chain densely functionalized polystyrene, suitable for ATRP grafting, was prepared by polymer-analogous reactions. Thereafter, monodisperse copolymers with acrylate were obtained.
  • The preparation of Br-terminated methyl methacrylate macronitiator (MI) from living precursors obtained by anionic or GTP polymerization was examined. Tranformation of the precursor end groups with bromine or N-bromosuccinimide, resp., afforded 60 % functionalization. MI was utilized in the synthesis of ABC triblock copolymers by ATRP. Another macroinitiator, a monodisperse, in-chain densely functionalized polystyrene, suitable for ATRP grafting, was prepared by polymer-analogous reactions. Thereafter, monodisperse copolymers with acrylate were obtained. (en)
Title
  • Tailoring of polymers by combination of ionic and radical controlled polymerizations.
  • Tailoring of polymers by combination of ionic and radical controlled polymerizations. (en)
skos:prefLabel
  • Tailoring of polymers by combination of ionic and radical controlled polymerizations.
  • Tailoring of polymers by combination of ionic and radical controlled polymerizations. (en)
skos:notation
  • RIV/61389013:_____/02:55023352!RIV/2003/AV0/A55003/N
http://linked.open.../vavai/riv/strany
  • 139;144
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(IAA4050009), P(OC P1.10), Z(AV0Z4050913)
http://linked.open...iv/cisloPeriodika
  • N/A
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 666345
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  • RIV/61389013:_____/02:55023352
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  • anionic polymerization; group transfer polymerization; atom transfer radical polymerization (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [192E32F25E59]
http://linked.open...i/riv/nazevZdroje
  • Macromolecular Symposia
http://linked.open...in/vavai/riv/obor
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 183
http://linked.open...iv/tvurceVysledku
  • Janata, Miroslav
  • Látalová, Petra
  • Vlček, Petr
  • Toman, Luděk
  • Masař, Bohumil
http://linked.open...n/vavai/riv/zamer
issn
  • 1022-1360
number of pages
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