About: Energy vs. entropy in cooperative electrostatic interactions: comparative study of binding of sodium poly(styrenesulfonate), dodecylbenzenesulfonate and methylbenzenesulfonate to polycations.

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About: Energy vs. entropy in cooperative electrostatic interactions: comparative study of binding of sodium poly(styrenesulfonate), dodecylbenzenesulfonate and methylbenzenesulfonate to polycations. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Cooperative interactions of three derivatives of sodium benzenesulfonate with polycations were studied. Different driving forces lead to differently pronounced cooperativity effects (strongest for entropy in poly(styrenesulfonate), medium for hydrophobic interaction energy in dodecylbenzenesulfonate and none in methylbenzenesulfonate). The tendency to cooperative behavior thus depends on a fine balance of thermodynamic factors. The study was done using multinuclear NMR, quantum-chemical calculations and electrostatic Poisson-Boltzmann calculations. Cooperative interactions of three derivatives of sodium benzenesulfonate with polycations were studied. Different driving forces lead to differently pronounced cooperativity effects (strongest for entropy in poly(styrenesulfonate), medium for hydrophobic interaction energy in dodecylbenzenesulfonate and none in methylbenzenesulfonate). The tendency to cooperative behavior thus depends on a fine balance of thermodynamic factors. The study was done using multinuclear NMR, quantum-chemical calculations and electrostatic Poisson-Boltzmann calculations. (en)
Title	Energy vs. entropy in cooperative electrostatic interactions: comparative study of binding of sodium poly(styrenesulfonate), dodecylbenzenesulfonate and methylbenzenesulfonate to polycations. Energy vs. entropy in cooperative electrostatic interactions: comparative study of binding of sodium poly(styrenesulfonate), dodecylbenzenesulfonate and methylbenzenesulfonate to polycations. (en)
skos:prefLabel	Energy vs. entropy in cooperative electrostatic interactions: comparative study of binding of sodium poly(styrenesulfonate), dodecylbenzenesulfonate and methylbenzenesulfonate to polycations. Energy vs. entropy in cooperative electrostatic interactions: comparative study of binding of sodium poly(styrenesulfonate), dodecylbenzenesulfonate and methylbenzenesulfonate to polycations. (en)
skos:notation	RIV/61389013:_____/02:55023005!RIV/2003/AV0/A55003/N
http://linked.open.../vavai/riv/strany	2175;2185
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(IAA4050206), P(KSK4050111), Z(AV0Z4050913)
http://linked.open...iv/cisloPeriodika	9
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Kurková, Dana Dybal, Jiří Kříž, Jaroslav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav makromolekulární chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	645044
http://linked.open...ai/riv/idVysledku	RIV/61389013:_____/02:55023005
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	cooperative interactions; electrostatic complexes; NMR (en)
http://linked.open.../riv/klicoveSlovo	NMR electrostatic complexes cooperative interactions
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[1CCB5809A877]
http://linked.open...i/riv/nazevZdroje	Journal of Physics and Chemistry. B
http://linked.open...in/vavai/riv/obor	CD
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Goal-oriented preparation of chemical compounds with well-defined properties Cooperative electrostatic interactions of macromolecules
http://linked.open...UplatneniVysledku	2002
http://linked.open...v/svazekPeriodika	106
http://linked.open...iv/tvurceVysledku	Dybal, Jiří Kříž, Jaroslav Kurková, Dana
http://linked.open...n/vavai/riv/zamer	Cílená syntéza a studium chemických, fyzikálně-chemických a fyzikálních vlastností makromolekulárních a nadmolekulárních látek a soustav pro vyspělé technologie
issn	1089-5647
number of pages	11 (xsd:int)

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