About: Molecular structure of the complex of hexano-6-lactam with magnesium bromide.     Goto   Sponge   NotDistinct   Permalink

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  • The structure of the complex of hexano-6-lactam (.epsilon.-caprolactam) with MgBr 2 was studied using 1 H, 13 C, 14 N, 15 N, 25 Mg and 79 Br NMR and FTIR spectroscopy. thermal analysis and ab initio 6-31G SCF quantum-mechanical calculations. The study established an unequivocal stable and highly symmetrical structure of the complex including MgBr 2 and six molecules of caprolactam. The result is important for the mechanism of anionic-coordination polymerization of lactams initiated with Grignard and related compounds.
  • The structure of the complex of hexano-6-lactam (.epsilon.-caprolactam) with MgBr 2 was studied using 1 H, 13 C, 14 N, 15 N, 25 Mg and 79 Br NMR and FTIR spectroscopy. thermal analysis and ab initio 6-31G SCF quantum-mechanical calculations. The study established an unequivocal stable and highly symmetrical structure of the complex including MgBr 2 and six molecules of caprolactam. The result is important for the mechanism of anionic-coordination polymerization of lactams initiated with Grignard and related compounds. (en)
Title
  • Molecular structure of the complex of hexano-6-lactam with magnesium bromide.
  • Molecular structure of the complex of hexano-6-lactam with magnesium bromide. (en)
skos:prefLabel
  • Molecular structure of the complex of hexano-6-lactam with magnesium bromide.
  • Molecular structure of the complex of hexano-6-lactam with magnesium bromide. (en)
skos:notation
  • RIV/61389013:_____/01:55010299!RIV/2003/AV0/A55003/N
http://linked.open.../vavai/riv/strany
  • 1194;1199
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA106/98/0699), P(KSK2050602), Z(AV0Z4050913)
http://linked.open...iv/cisloPeriodika
  • 7
http://linked.open...vai/riv/dodaniDat
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  • 687582
http://linked.open...ai/riv/idVysledku
  • RIV/61389013:_____/01:55010299
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  • anionic-coordination polymerization; lactams; magnesium bromide (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [EADA313637A5]
http://linked.open...i/riv/nazevZdroje
  • Macromolecular Chemistry and Physics
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...v/svazekPeriodika
  • 202
http://linked.open...iv/tvurceVysledku
  • Dybal, Jiří
  • Kříž, Jaroslav
  • Kurková, Dana
  • Brožek, J.
  • Prokopová, I.
  • Arnoldová, P.
  • Hroch, Z.
http://linked.open...n/vavai/riv/zamer
issn
  • 1022-1352
number of pages
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