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Description
  • The surface tension of liquid clusters in the Classical Nucleation Theory (CNT) is investigated using the Gibbs adsorption isotherm. A theoretical derivation is given that shows the relation between macroscopic (plain-surface) surface tension and the surface tension of microscopic spherical clusters of the CNT. An exemplary water – ethanol binary condensing system is studied. It is shown that by using the microscopic surface tension in nucleation calculations an exceptional agreement between theoretical and experimental nucleation rates is achieved.
  • The surface tension of liquid clusters in the Classical Nucleation Theory (CNT) is investigated using the Gibbs adsorption isotherm. A theoretical derivation is given that shows the relation between macroscopic (plain-surface) surface tension and the surface tension of microscopic spherical clusters of the CNT. An exemplary water – ethanol binary condensing system is studied. It is shown that by using the microscopic surface tension in nucleation calculations an exceptional agreement between theoretical and experimental nucleation rates is achieved. (en)
Title
  • Microscopic Surface Tension in the Classical Nucleation Theory
  • Microscopic Surface Tension in the Classical Nucleation Theory (en)
skos:prefLabel
  • Microscopic Surface Tension in the Classical Nucleation Theory
  • Microscopic Surface Tension in the Classical Nucleation Theory (en)
skos:notation
  • RIV/61388998:_____/09:00329360!RIV10-AV0-61388998
http://linked.open...avai/riv/aktivita
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  • P(KJB400760701), Z(AV0Z20760514)
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  • 326221
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  • RIV/61388998:_____/09:00329360
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  • nucleation theory; multicomponent condensation; surface adsorption (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [099842D53FFF]
http://linked.open...v/mistoKonaniAkce
  • Praha
http://linked.open...i/riv/mistoVydani
  • Praha
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  • Nucleation and Atmospheric Aerosol
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  • Maršík, František
  • Němec, Tomáš
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http://linked.open...n/vavai/riv/zamer
number of pages
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  • Institute of Chemical Process Fundamentals ASCR, v.v, Czech Aerosol Society
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  • 978-80-02-12161-2
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