About: N-Allyl-N-methylpiperidinium bis(trifluoromethanesulfonyl)imide-A film forming ionic liquid for graphite anode of Li-ion batteries

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About: N-Allyl-N-methylpiperidinium bis(trifluoromethanesulfonyl)imide-A film forming ionic liquid for graphite anode of Li-ion batteries Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	An ionic liquid. N-allyl-N-methylpiperidinium bis(trifluoromethanesulfonyl)imide PP13 center dot TFSI has been successfully tested as a solid electrolyte interface (SEI) forming agent for graphite composite anode at elevated temperature of 55 degrees C in a purely ionic liquid-based electrolyte: 0.5 m LiTFSI in a mixture of PP13 center dot TFSI-PP13TFSI (20-80 wt.%) The reversible discharge capacity was 340-350 mAh g(-1) with only a small irreversible capacity loss per cycle. The electrochemical polymerisation of the allylic double bond participates on the SEI formation on the graphite surface. In the absence of unsaturated ionic liquid, the piperidinium cation is co-intercalated into graphite and causes its exfoliation with permanent loss of capacity. The electrolyte is thermally stable up to 320 degrees C and reasonably conductive (2.4 mS cm(-1) at 55 degrees C). An ionic liquid. N-allyl-N-methylpiperidinium bis(trifluoromethanesulfonyl)imide PP13 center dot TFSI has been successfully tested as a solid electrolyte interface (SEI) forming agent for graphite composite anode at elevated temperature of 55 degrees C in a purely ionic liquid-based electrolyte: 0.5 m LiTFSI in a mixture of PP13 center dot TFSI-PP13TFSI (20-80 wt.%) The reversible discharge capacity was 340-350 mAh g(-1) with only a small irreversible capacity loss per cycle. The electrochemical polymerisation of the allylic double bond participates on the SEI formation on the graphite surface. In the absence of unsaturated ionic liquid, the piperidinium cation is co-intercalated into graphite and causes its exfoliation with permanent loss of capacity. The electrolyte is thermally stable up to 320 degrees C and reasonably conductive (2.4 mS cm(-1) at 55 degrees C). (en)
Title	N-Allyl-N-methylpiperidinium bis(trifluoromethanesulfonyl)imide-A film forming ionic liquid for graphite anode of Li-ion batteries N-Allyl-N-methylpiperidinium bis(trifluoromethanesulfonyl)imide-A film forming ionic liquid for graphite anode of Li-ion batteries (en)
skos:prefLabel	N-Allyl-N-methylpiperidinium bis(trifluoromethanesulfonyl)imide-A film forming ionic liquid for graphite anode of Li-ion batteries N-Allyl-N-methylpiperidinium bis(trifluoromethanesulfonyl)imide-A film forming ionic liquid for graphite anode of Li-ion batteries (en)
skos:notation	RIV/61388980:_____/12:00387933!RIV13-AV0-61388980
http://linked.open...avai/predkladatel	Ústav anorganické chemie AV ČR, v.v.i.
http://linked.open...avai/riv/aktivita	I P Z
http://linked.open...avai/riv/aktivity	I, P(KJB200320801), P(KJB200320901), Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika	JUNE
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Reiter, Jakub
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	152881
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/12:00387933
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Bis(trifluoromethansulfonyl)imide; Unsaturated piperidinium ionic liquid; Graphite; Solid electrolyte interface; Lithium-ion battery (en)
http://linked.open.../riv/klicoveSlovo	Graphite Lithium-ion battery Solid electrolyte interface Bis(trifluoromethansulfonyl)imide Unsaturated piperidinium ionic liquid
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[8D51A6591163]
http://linked.open...i/riv/nazevZdroje	Electrochimica acta
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...vavai/riv/projekt	Nanostructured doped oxides prepared from the medium of lyotropic liquid crystals Miniaturised electrochemical gas sensors
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	71
http://linked.open...iv/tvurceVysledku	Reiter, Jakub Nádherná, M.
http://linked.open...ain/vavai/riv/wos	000304510900004
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí
issn	0013-4686
number of pages	5 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.electacta.2012.03.088
is http://linked.open...avai/riv/vysledek of	N-Allyl-N-methylpiperidinium bis(trifluoromethanesulfonyl)imide-A film forming ionic liquid for graphite anode of Li-ion batteries

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