About: Macropolyhedral boron-containing cluster chemistry [S2B16H17](-). A new eighteen-vertex thiaborane anion     Goto   Sponge   NotDistinct   Permalink

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  • The novel eighteen-vertex macropolyhedral dithiaborane anion [S2B16H17](-) 1 has been obtained as its [tmndH](+) salt from the reaction of [S2B17H17] 2 and tmnd in solution in the presence of [RhCl2(eta(5)-C5Me5)](2). It has two cluster skeletal electrons more than the three previously reported eighteen-vertex dithiaborane {S2B16} species n-[S2B16H16], n-[S2B16H15](-) and iso-[S2B16H16], and the anion consists structurally of an arachno {SB9} and a nido {B-9} cluster unit fused with two boron atoms in common, and with an endo-to-exo sulfur bridge that also links the two subclusters together.
  • The novel eighteen-vertex macropolyhedral dithiaborane anion [S2B16H17](-) 1 has been obtained as its [tmndH](+) salt from the reaction of [S2B17H17] 2 and tmnd in solution in the presence of [RhCl2(eta(5)-C5Me5)](2). It has two cluster skeletal electrons more than the three previously reported eighteen-vertex dithiaborane {S2B16} species n-[S2B16H16], n-[S2B16H15](-) and iso-[S2B16H16], and the anion consists structurally of an arachno {SB9} and a nido {B-9} cluster unit fused with two boron atoms in common, and with an endo-to-exo sulfur bridge that also links the two subclusters together. (en)
Title
  • Macropolyhedral boron-containing cluster chemistry [S2B16H17](-). A new eighteen-vertex thiaborane anion
  • Macropolyhedral boron-containing cluster chemistry [S2B16H17](-). A new eighteen-vertex thiaborane anion (en)
skos:prefLabel
  • Macropolyhedral boron-containing cluster chemistry [S2B16H17](-). A new eighteen-vertex thiaborane anion
  • Macropolyhedral boron-containing cluster chemistry [S2B16H17](-). A new eighteen-vertex thiaborane anion (en)
skos:notation
  • RIV/61388980:_____/10:00357559!RIV11-AV0-61388980
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika
  • 8
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
  • Londesborough, Michael Geoffrey Stephen
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 269119
http://linked.open...ai/riv/idVysledku
  • RIV/61388980:_____/10:00357559
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • borane cluster; thiaborane; macropolyhedral (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [CFDD7A0A268B]
http://linked.open...i/riv/nazevZdroje
  • Collection of Czechoslovak Chemical Communications
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 75
http://linked.open...iv/tvurceVysledku
  • Kennedy, J. D.
  • Londesborough, Michael Geoffrey Stephen
  • Clegg, W.
  • Carr, M. J.
  • Kilner, C. A.
http://linked.open...ain/vavai/riv/wos
  • 000281958400003
http://linked.open...n/vavai/riv/zamer
issn
  • 0010-0765
number of pages
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