About: Macropolyhedral boron-containing cluster chemistry. Metallathiaboranes from S2B17H17: isolation and characterisation of [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B16H16] and [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B15H15]

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About: Macropolyhedral boron-containing cluster chemistry. Metallathiaboranes from S2B17H17: isolation and characterisation of [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B16H16] and [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B15H15] Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Deprotonation of [S2B17H17] 1 with NaH and subsequent reaction with [{RuCl2(eta(6)-MeC6H4 Pr-iso)}(2)] gives new nineteen-vertex [(eta(6)- MeC6H4 Pr-iso) RuS2B16H16] 2, with a nido {SB9} unit and an arachno-type {RuSB9} unit conjoined with a B - B edge in common, and new eighteen-vertex [(eta(6)-MeC6H4 Pr-iso) RuS2B15H15] 3 with a nido {RuSB9} subcluster fused via a common B - B edge to a nido {B-8} subcluster that is additionally linked exo to the {RuSB9} unit by a bridging sulfur atom that is held endo to the {B-8} unit. Deprotonation of [S2B17H17] 1 with NaH and subsequent reaction with [{RuCl2(eta(6)-MeC6H4 Pr-iso)}(2)] gives new nineteen-vertex [(eta(6)- MeC6H4 Pr-iso) RuS2B16H16] 2, with a nido {SB9} unit and an arachno-type {RuSB9} unit conjoined with a B - B edge in common, and new eighteen-vertex [(eta(6)-MeC6H4 Pr-iso) RuS2B15H15] 3 with a nido {RuSB9} subcluster fused via a common B - B edge to a nido {B-8} subcluster that is additionally linked exo to the {RuSB9} unit by a bridging sulfur atom that is held endo to the {B-8} unit. (en) Chemie makropolyhedrálních klastrů obsahujících bor. Metallathiaborany odvozené z S2B17H17: izolace a charakterizace. (cs)
Title	Macropolyhedral boron-containing cluster chemistry. Metallathiaboranes from S2B17H17: isolation and characterisation of [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B16H16] and [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B15H15] Chemie makropolyhedrálních klastrů obsahujících bor.Metallathiaborany odvozené z S2B17H17: izolace a charakterizace (cs) Macropolyhedral boron-containing cluster chemistry. Metallathiaboranes from S2B17H17: isolation and characterisation of [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B16H16] and [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B15H15] (en)
skos:prefLabel	Macropolyhedral boron-containing cluster chemistry. Metallathiaboranes from S2B17H17: isolation and characterisation of [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B16H16] and [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B15H15] Chemie makropolyhedrálních klastrů obsahujících bor.Metallathiaborany odvozené z S2B17H17: izolace a charakterizace (cs) Macropolyhedral boron-containing cluster chemistry. Metallathiaboranes from S2B17H17: isolation and characterisation of [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B16H16] and [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B15H15] (en)
skos:notation	RIV/61388980:_____/06:00050989!RIV07-AV0-61388980
http://linked.open.../vavai/riv/strany	3624;3626
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika	30
http://linked.open...vai/riv/dodaniDat	2007
http://linked.open...aciTvurceVysledku	Londesborough, Michael Geoffrey Stephen
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	483816
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/06:00050989
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	anion; metallaboranes; thiaborane (en)
http://linked.open.../riv/klicoveSlovo	anion metallaboranes thiaborane
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[CFBB76FE9484]
http://linked.open...i/riv/nazevZdroje	Dalton Transactions
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...UplatneniVysledku	2006
http://linked.open...v/svazekPeriodika	-
http://linked.open...iv/tvurceVysledku	Kennedy, J. D. Londesborough, Michael Geoffrey Stephen Carr, M. J. McLeod, A. R. H.
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí
issn	1477-9226
number of pages	3 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Macropolyhedral boron-containing cluster chemistry. Metallathiaboranes from S2B17H17: isolation and characterisation of [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B16H16] and [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B15H15] Macropolyhedral boron-containing cluster chemistry. Metallathiaboranes from S2B17H17: isolation and characterisation of [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B16H16] and [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B15H15]

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