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  • Glass formation has been investigated in the Sb2O3-ZnBr2 binary system. Vitreous samples have been obtained for batches containing 20-90 mol% Sb2O3. Chemical analysis shows that bromine concentration is smaller than expected and real compositions belong to the Sb2O3-ZnBr2-ZnO ternary system. However, the discrepancy between nominal and analyzed compositions is fair for Sb2O3 content larger than 50 mol%. Optical transmission lies between 400 nm and 7 mum and refractive index ranges from 2.0 to 2.1. Glass transition occurs around 300 degreesC, and crystallization exotherm does not appear in the differential scanning calorimetry scan at 10 K s(-1) for samples containing 50-60 mol% Sb2O3. Thermal expansion varies between 120 and 220 x 10(-7) K-1 as antimony content decreases. Microhardness is close to 200 kg/mm(2). These glasses have low phonon energy and make potential materials for infrared transmission and active fibers.
  • Glass formation has been investigated in the Sb2O3-ZnBr2 binary system. Vitreous samples have been obtained for batches containing 20-90 mol% Sb2O3. Chemical analysis shows that bromine concentration is smaller than expected and real compositions belong to the Sb2O3-ZnBr2-ZnO ternary system. However, the discrepancy between nominal and analyzed compositions is fair for Sb2O3 content larger than 50 mol%. Optical transmission lies between 400 nm and 7 mum and refractive index ranges from 2.0 to 2.1. Glass transition occurs around 300 degreesC, and crystallization exotherm does not appear in the differential scanning calorimetry scan at 10 K s(-1) for samples containing 50-60 mol% Sb2O3. Thermal expansion varies between 120 and 220 x 10(-7) K-1 as antimony content decreases. Microhardness is close to 200 kg/mm(2). These glasses have low phonon energy and make potential materials for infrared transmission and active fibers. (en)
Title
  • Glass formation in the Sb2O3-ZnBr2 binary
  • Glass formation in the Sb2O3-ZnBr2 binary (en)
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  • Glass formation in the Sb2O3-ZnBr2 binary
  • Glass formation in the Sb2O3-ZnBr2 binary (en)
skos:notation
  • RIV/61388980:_____/04:00340219!RIV10-AV0-61388980
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z4032918)
http://linked.open...iv/cisloPeriodika
  • 5
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...dnocenehoVysledku
  • 565591
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  • RIV/61388980:_____/04:00340219
http://linked.open...riv/jazykVysledku
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  • fluoride; SB2O3 (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [B16E7ABB8741]
http://linked.open...i/riv/nazevZdroje
  • Journal of Physics and Chemistry of Solids
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 65
http://linked.open...iv/tvurceVysledku
  • Kostka, Petr
  • Poulain, M.
  • Legouera, M.
http://linked.open...ain/vavai/riv/wos
  • 000220412100009
http://linked.open...n/vavai/riv/zamer
issn
  • 0022-3697
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