About: Asymmetric Transfer Hydrogenation of Acetophenone N-Benzylimine Using [(RuCl)-Cl-II((S,S)-TsDPEN)(eta(6)-p-cymene)]: A DFT Study     Goto   Sponge   NotDistinct   Permalink

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  • Asymmetric transfer hydrogenation of the acyclic imine acetophenone N-benzylimine was studied by means of computational chemistry. Calculated transition states offer an explanation of why this prochiral imine leads to the delivery of (S)-amine (when using (S,S)-TsDPEN ligand) rather than (R)-amine, which is common for endocyclic imines (e.g., substituted 3,4-dihydroisoquinolines or 3,4-dihydro-beta-carbolines). This study extends our previous investigation of the so-called ionic mechanism
  • Asymmetric transfer hydrogenation of the acyclic imine acetophenone N-benzylimine was studied by means of computational chemistry. Calculated transition states offer an explanation of why this prochiral imine leads to the delivery of (S)-amine (when using (S,S)-TsDPEN ligand) rather than (R)-amine, which is common for endocyclic imines (e.g., substituted 3,4-dihydroisoquinolines or 3,4-dihydro-beta-carbolines). This study extends our previous investigation of the so-called ionic mechanism (en)
Title
  • Asymmetric Transfer Hydrogenation of Acetophenone N-Benzylimine Using [(RuCl)-Cl-II((S,S)-TsDPEN)(eta(6)-p-cymene)]: A DFT Study
  • Asymmetric Transfer Hydrogenation of Acetophenone N-Benzylimine Using [(RuCl)-Cl-II((S,S)-TsDPEN)(eta(6)-p-cymene)]: A DFT Study (en)
skos:prefLabel
  • Asymmetric Transfer Hydrogenation of Acetophenone N-Benzylimine Using [(RuCl)-Cl-II((S,S)-TsDPEN)(eta(6)-p-cymene)]: A DFT Study
  • Asymmetric Transfer Hydrogenation of Acetophenone N-Benzylimine Using [(RuCl)-Cl-II((S,S)-TsDPEN)(eta(6)-p-cymene)]: A DFT Study (en)
skos:notation
  • RIV/61388971:_____/12:00390161!RIV13-GA0-61388971
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  • I, P(GA104/09/1497), P(GAP106/12/1276)
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  • 17
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  • 123956
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  • RIV/61388971:_____/12:00390161
http://linked.open...riv/jazykVysledku
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  • CARBONYL-COMPOUNDS; KETONES; IMINES (en)
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  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [36F9D4F64C79]
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  • Organometallics
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  • 31
http://linked.open...iv/tvurceVysledku
  • Kačer, P.
  • Kuzma, Marek
  • Václavík, J.
  • Januščák, J.
  • Pecháček, J.
  • Přech, J.
  • Šot, P.
http://linked.open...ain/vavai/riv/wos
  • 000308513000064
issn
  • 0276-7333
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/om300413n
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