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rdf:type
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Description
| - A short and efficient synthesis of the pentacyclic core of the indole alkaloid tronocarpine is described. The synthetic pathway involves several easily accomplished steps, including a radical oxidative aromatic substitution reaction on the N-tert-butoxycarbonyl-protected tryptamine and a xanthate, a 1,4-1,2-nucleophilic addition between a 2,3-disubstituted indole and an ,-unsaturated aldehyde, and a Ti-mediated Dieckmann condensation. This report represents a significant advance in the quest for the first total synthesis of tronocarpine.
- A short and efficient synthesis of the pentacyclic core of the indole alkaloid tronocarpine is described. The synthetic pathway involves several easily accomplished steps, including a radical oxidative aromatic substitution reaction on the N-tert-butoxycarbonyl-protected tryptamine and a xanthate, a 1,4-1,2-nucleophilic addition between a 2,3-disubstituted indole and an ,-unsaturated aldehyde, and a Ti-mediated Dieckmann condensation. This report represents a significant advance in the quest for the first total synthesis of tronocarpine. (en)
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Title
| - Synthesis of the Pentacyclic Framework of the Alkaloid Tronocarpine
- Synthesis of the Pentacyclic Framework of the Alkaloid Tronocarpine (en)
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skos:prefLabel
| - Synthesis of the Pentacyclic Framework of the Alkaloid Tronocarpine
- Synthesis of the Pentacyclic Framework of the Alkaloid Tronocarpine (en)
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skos:notation
| - RIV/61388963:_____/14:00427580!RIV15-AV0-61388963
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
| - Reyes Gutierrez, Paul Eduardo
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388963:_____/14:00427580
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - natural products; alkaloids; radicals; nucleophilic addition; cyclization (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - DE - Spolková republika Německo
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - European Journal of Organic Chemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Reyes Gutierrez, Paul Eduardo
- Martínez, R.
- Torres-Ochoa, R. O.
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
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