About: Formation of n-Alkyl Monolayers by Organomercury Deposition on Gold

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	n-Alkyl self-assembled monolayers can be directly attached to gold through C-Au bonds by the deposition of organomercury salts on gold substrates, as shown here using n-butylmercury and n-octadecylmercury tosylate derivatives. The Hg atoms, which are codeposited during this process, are removed by thermal annealing at 95 degrees C, resulting in alkyl monolayers having a significantly enhanced thermal stability compared with alkanethiol monolayers, however, a lower degree of conformational order. The monolayer properties are elucidated by X-ray photoemission and IR spectroscopy, STM, ellipsometry, and contact-angle goniometry. n-Alkyl self-assembled monolayers can be directly attached to gold through C-Au bonds by the deposition of organomercury salts on gold substrates, as shown here using n-butylmercury and n-octadecylmercury tosylate derivatives. The Hg atoms, which are codeposited during this process, are removed by thermal annealing at 95 degrees C, resulting in alkyl monolayers having a significantly enhanced thermal stability compared with alkanethiol monolayers, however, a lower degree of conformational order. The monolayer properties are elucidated by X-ray photoemission and IR spectroscopy, STM, ellipsometry, and contact-angle goniometry. (en)
Title	Formation of n-Alkyl Monolayers by Organomercury Deposition on Gold Formation of n-Alkyl Monolayers by Organomercury Deposition on Gold (en)
skos:prefLabel	Formation of n-Alkyl Monolayers by Organomercury Deposition on Gold Formation of n-Alkyl Monolayers by Organomercury Deposition on Gold (en)
skos:notation	RIV/61388963:_____/13:00396250!RIV14-GA0-61388963
http://linked.open...avai/predkladatel	Ústav organické chemie a biochemie AV ČR, v. v. i.
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(GA203/07/1619), P(GA203/09/0705)
http://linked.open...iv/cisloPeriodika	16
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Kaletová, Eva Stibor, Ivan Kohutová, Anna Michl, Josef Mucha, Malgorzata Stensrud, Elizabeth
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav organické chemie a biochemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	75523
http://linked.open...ai/riv/idVysledku	RIV/61388963:_____/13:00396250
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	self-assembled monolayers; ray photoelectron-spectroscopy; altitudinal molecular rotors (en)
http://linked.open.../riv/klicoveSlovo	ray photoelectron-spectroscopy altitudinal molecular rotors self-assembled monolayers
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[93E0E6DB5160]
http://linked.open...i/riv/nazevZdroje	Journal of Physical Chemistry Letters
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	6 (xsd:int)
http://linked.open...cetTvurcuVysledku	9 (xsd:int)
http://linked.open...vavai/riv/projekt	New structures for self-assembled monolayers Transfer of charge in single and assembled molecules
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	4
http://linked.open...iv/tvurceVysledku	Michl, Josef Scholz, F. Wrochem von, F. Stibor, Ivan Kohutová, Anna Kaletová, Eva Mucha, Malgorzata Stensrud, Elizabeth Ford, W. E.
http://linked.open...ain/vavai/riv/wos	000323300900005
issn	1948-7185
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1021/jz4011898

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