About: The synthesis of pi-electron molecular rods with a thiophene or thieno[3,2-b]thiophene core unit and sulfur alligator clips     Goto   Sponge   NotDistinct   Permalink

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Description
  • A series of short oligo(p-phenylene-ethynylene)- and oligo(p-phenylenevinylene)-type molecular rods with an electronically rich thiophene or thieno[3,2-b]thiophene core unit and sulfur anchoring groups (AcS-, t-BuS-) at the termini have been synthesised using Sonogashira coupling or Homer-Wads-worth-Emmons (E)-olefination methodology. The collection of linear/bent, conjugated/cross-conjugated systems has been characterised by UV-vis and fluorescence spectroscopy, optical/calculated HOMO-LUMO gaps and calculated excitation energies.
  • A series of short oligo(p-phenylene-ethynylene)- and oligo(p-phenylenevinylene)-type molecular rods with an electronically rich thiophene or thieno[3,2-b]thiophene core unit and sulfur anchoring groups (AcS-, t-BuS-) at the termini have been synthesised using Sonogashira coupling or Homer-Wads-worth-Emmons (E)-olefination methodology. The collection of linear/bent, conjugated/cross-conjugated systems has been characterised by UV-vis and fluorescence spectroscopy, optical/calculated HOMO-LUMO gaps and calculated excitation energies. (en)
Title
  • The synthesis of pi-electron molecular rods with a thiophene or thieno[3,2-b]thiophene core unit and sulfur alligator clips
  • The synthesis of pi-electron molecular rods with a thiophene or thieno[3,2-b]thiophene core unit and sulfur alligator clips (en)
skos:prefLabel
  • The synthesis of pi-electron molecular rods with a thiophene or thieno[3,2-b]thiophene core unit and sulfur alligator clips
  • The synthesis of pi-electron molecular rods with a thiophene or thieno[3,2-b]thiophene core unit and sulfur alligator clips (en)
skos:notation
  • RIV/61388963:_____/13:00393043!RIV14-AV0-61388963
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • I, P(IAA400550919)
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  • 22
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  • 109548
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  • RIV/61388963:_____/13:00393043
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  • molecular wires; thiophene OPE rods; thiophene OPV rods; UV spectra; HOMO-LUMO gaps (en)
http://linked.open.../riv/klicoveSlovo
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  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [74656821DDDB]
http://linked.open...i/riv/nazevZdroje
  • Tetrahedron Letters
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  • 54
http://linked.open...iv/tvurceVysledku
  • Vacek, Jaroslav
  • Stará, Irena G.
  • Starý, Ivo
  • Svoboda, J.
  • Vacek Chocholoušová, Jana
  • Dekoj, Václav
  • Seidler, A.
http://linked.open...ain/vavai/riv/wos
  • 000318664900011
issn
  • 0040-4039
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.tetlet.2013.03.084
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