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  • Pyrogallol[4]arene is a macrocycle with a concave surface and 12 peripheral hydroxyl groups that mediate its self-assembly to form hexamers of octahedral symmetry in the solid state, in solution, and in the gas phase. In this study, we show that solvent-free conditions for guest entrapment in these hexamers, using molten guest molecules as solvent and allowing the capsules to assemble during cooling, results in exceptionally kinetically stable encapsulation complexes that are not formed in the presence of solvent and are not thermodynamically stable.
  • Pyrogallol[4]arene is a macrocycle with a concave surface and 12 peripheral hydroxyl groups that mediate its self-assembly to form hexamers of octahedral symmetry in the solid state, in solution, and in the gas phase. In this study, we show that solvent-free conditions for guest entrapment in these hexamers, using molten guest molecules as solvent and allowing the capsules to assemble during cooling, results in exceptionally kinetically stable encapsulation complexes that are not formed in the presence of solvent and are not thermodynamically stable. (en)
Title
  • Molecular Encapsulation in Pyrogallolarene Hexamers Under Nonequilibrium Conditions
  • Molecular Encapsulation in Pyrogallolarene Hexamers Under Nonequilibrium Conditions (en)
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  • Molecular Encapsulation in Pyrogallolarene Hexamers Under Nonequilibrium Conditions
  • Molecular Encapsulation in Pyrogallolarene Hexamers Under Nonequilibrium Conditions (en)
skos:notation
  • RIV/61388963:_____/12:00380643!RIV13-AV0-61388963
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http://linked.open...avai/riv/aktivita
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  • Z(AV0Z40550506)
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  • 36
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  • 151538
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  • RIV/61388963:_____/12:00380643
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  • pyrogallol[4]arene; hexamer; encapsulation; guest exchange (en)
http://linked.open.../riv/klicoveSlovo
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  • US - Spojené státy americké
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  • [BE224A9BBA8E]
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  • Journal of the American Chemical Society
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  • 134
http://linked.open...iv/tvurceVysledku
  • Kvasnica, Miroslav
  • Chapin, J. C.
  • Purse, B. W.
http://linked.open...ain/vavai/riv/wos
  • 000308574800058
http://linked.open...n/vavai/riv/zamer
issn
  • 0002-7863
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/ja305252t
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