About: Preparation of Covalent Long-Chain Trialkylstannyl and Trialkylsilyl Salts and an Examination of their Adsorption on Gold     Goto   Sponge   NotDistinct   Permalink

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  • We report the attachment of alkyl residues to a gold surface through a tin atom. Covalent trialkylstannyl and trialkylsilyl salts of trifluoromethanesulfonic, trifluoroacetic, and p-toluenesulfonic acids containing one to three C18H37 chains and two to noCH3 groups in the molecule have been synthesized. They were tested for adsorption on gold from solution under ambient conditions using ellipsometry, FTIR spectroscopy, contact angle, and electrode-blocking measurements. All nine trialkylstannyl salts form similar stable monolayers with the loss of the acid residue and form no multilayers.
  • We report the attachment of alkyl residues to a gold surface through a tin atom. Covalent trialkylstannyl and trialkylsilyl salts of trifluoromethanesulfonic, trifluoroacetic, and p-toluenesulfonic acids containing one to three C18H37 chains and two to noCH3 groups in the molecule have been synthesized. They were tested for adsorption on gold from solution under ambient conditions using ellipsometry, FTIR spectroscopy, contact angle, and electrode-blocking measurements. All nine trialkylstannyl salts form similar stable monolayers with the loss of the acid residue and form no multilayers. (en)
Title
  • Preparation of Covalent Long-Chain Trialkylstannyl and Trialkylsilyl Salts and an Examination of their Adsorption on Gold
  • Preparation of Covalent Long-Chain Trialkylstannyl and Trialkylsilyl Salts and an Examination of their Adsorption on Gold (en)
skos:prefLabel
  • Preparation of Covalent Long-Chain Trialkylstannyl and Trialkylsilyl Salts and an Examination of their Adsorption on Gold
  • Preparation of Covalent Long-Chain Trialkylstannyl and Trialkylsilyl Salts and an Examination of their Adsorption on Gold (en)
skos:notation
  • RIV/61388963:_____/10:00352059!RIV11-GA0-61388963
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/07/1619), Z(AV0Z40550506)
http://linked.open...iv/cisloPeriodika
  • 11
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 281360
http://linked.open...ai/riv/idVysledku
  • RIV/61388963:_____/10:00352059
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • thin films; tin organometallics (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [354F13036693]
http://linked.open...i/riv/nazevZdroje
  • Langmuir
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 26
http://linked.open...iv/tvurceVysledku
  • Michl, Josef
  • Pohl, Radek
  • Stibor, Ivan
  • Khobragade, Dushant
  • Mucha, Malgorzata
  • Stensrud, Elizabeth
  • Smith, Joshua R.
http://linked.open...ain/vavai/riv/wos
  • 000277928100110
http://linked.open...n/vavai/riv/zamer
issn
  • 0743-7463
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