About: An effective hydrolysis of crowded chiral esters.

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About: An effective hydrolysis of crowded chiral esters. Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Trifluoromethanesulfonic acid-coated silica in the absence of solvents is an effective reagent for hydrolysis of sterically crowded chiral esters giving chiral acids in good chemical and optical yield. On the other hand, the method was unsuitable for the separation of optically pure alcohols from chiral esters because dehydration usually takes place during the reaction course. Trifluoromethanesulfonic acid-coated silica in the absence of solvents is an effective reagent for hydrolysis of sterically crowded chiral esters giving chiral acids in good chemical and optical yield. On the other hand, the method was unsuitable for the separation of optically pure alcohols from chiral esters because dehydration usually takes place during the reaction course. (en)
Title	An effective hydrolysis of crowded chiral esters. An effective hydrolysis of crowded chiral esters. (en)
skos:prefLabel	An effective hydrolysis of crowded chiral esters. An effective hydrolysis of crowded chiral esters. (en)
skos:notation	RIV/61388963:_____/02:57020354!RIV/2003/AV0/A57003/N
http://linked.open.../vavai/riv/strany	1886;1888
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/01/0116), Z(AV0Z4055905)
http://linked.open...iv/cisloPeriodika	11
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Buděšínský, Miloš Vodička, Petr Vávra, Jan Koutek, Bohumír Streinz, Ludvík
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav organické chemie a biochemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	637961
http://linked.open...ai/riv/idVysledku	RIV/61388963:_____/02:57020354
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	trifluoromethanesulfonic acid (en)
http://linked.open.../riv/klicoveSlovo	trifluoromethanesulfonic acid
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[5450D1484E30]
http://linked.open...i/riv/nazevZdroje	Synlett
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Analysis of chiral compounds in non-chiral environment
http://linked.open...UplatneniVysledku	2002
http://linked.open...v/svazekPeriodika	N/A
http://linked.open...iv/tvurceVysledku	Buděšínský, Miloš Vávra, Jan Vodička, Petr Koutek, Bohumír Streinz, Ludvík
http://linked.open...n/vavai/riv/zamer	Chemical principles of selected biological phenomena in medicine and ecology
issn	0936-5214
number of pages	3 (xsd:int)

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