About: Identifying Intermediates of Sequential Electron and Hydrogen Loss from a Dicarbonylcobalt Hydride Complex     Goto   Sponge   NotDistinct   Permalink

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  • Coordination compounds of cobalt have recently received special attention in the context of hydrogen production (%22splitting water with cobalt%22)[1] and conversion.[1–9] Within these studies the mechanistic sequence of electron and proton or hydrogen transfer has frequently been discussed. Although cobalt carbonyl hydrides, especially [Co(CO)4H] have been the subject of many studies since their development by Hieber and co-workers in the 1930s[10] and since their use in hydroformylation processes, the hydrogen-producing reactions were mainly reported with non-organometallic cobalt complexes, involving ligands such as oligodentate imines, glyoximes, phosphanes, and macrocycles.[1–8]
  • Coordination compounds of cobalt have recently received special attention in the context of hydrogen production (%22splitting water with cobalt%22)[1] and conversion.[1–9] Within these studies the mechanistic sequence of electron and proton or hydrogen transfer has frequently been discussed. Although cobalt carbonyl hydrides, especially [Co(CO)4H] have been the subject of many studies since their development by Hieber and co-workers in the 1930s[10] and since their use in hydroformylation processes, the hydrogen-producing reactions were mainly reported with non-organometallic cobalt complexes, involving ligands such as oligodentate imines, glyoximes, phosphanes, and macrocycles.[1–8] (en)
Title
  • Identifying Intermediates of Sequential Electron and Hydrogen Loss from a Dicarbonylcobalt Hydride Complex
  • Identifying Intermediates of Sequential Electron and Hydrogen Loss from a Dicarbonylcobalt Hydride Complex (en)
skos:prefLabel
  • Identifying Intermediates of Sequential Electron and Hydrogen Loss from a Dicarbonylcobalt Hydride Complex
  • Identifying Intermediates of Sequential Electron and Hydrogen Loss from a Dicarbonylcobalt Hydride Complex (en)
skos:notation
  • RIV/61388955:_____/13:00394905!RIV14-MSM-61388955
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  • I, P(LD11086)
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  • 26
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  • 78771
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  • RIV/61388955:_____/13:00394905
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  • cobalt; Electron transfer; ferrocene (en)
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  • DE - Spolková republika Německo
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  • Angewandte Chemie. International Edition in English
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  • 52
http://linked.open...iv/tvurceVysledku
  • Fiedler, Jan
  • Kaim, W.
  • Záliš, Stanislav
  • Paretzki, A.
  • Bubrin, M.
  • Krafft, M. J.
  • Lissner, F.
http://linked.open...ain/vavai/riv/wos
  • 000320733600043
issn
  • 1433-7851
number of pages
http://bibframe.org/vocab/doi
  • 10.1002/anie.201301706
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