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  • The adsorption behaviour of a dinitroaniline herbicide benfluralin was studied by means of electrochemical as well as scanning probe techniques. The double layer capacitance reflects very sensitively changes of the interfacial structure at the surfaces. This allows discrimination between a simple adsorption process and a slow transition of adsorbed film structure controlled by the mechanism of nucleation. The information about nucleation kinetics and growth mechanism of the film on the electrode was obtained from the time dependence of the double layer capacitance employing the mercury drop electrode. The phase transition may lead to the reorientation of the molecules within the adsorbed layer. These findings were supported by scanning tunneling microscopy.
  • The adsorption behaviour of a dinitroaniline herbicide benfluralin was studied by means of electrochemical as well as scanning probe techniques. The double layer capacitance reflects very sensitively changes of the interfacial structure at the surfaces. This allows discrimination between a simple adsorption process and a slow transition of adsorbed film structure controlled by the mechanism of nucleation. The information about nucleation kinetics and growth mechanism of the film on the electrode was obtained from the time dependence of the double layer capacitance employing the mercury drop electrode. The phase transition may lead to the reorientation of the molecules within the adsorbed layer. These findings were supported by scanning tunneling microscopy. (en)
Title
  • Adsorption of pesticide benfluralin at the electrochemical interface
  • Adsorption of pesticide benfluralin at the electrochemical interface (en)
skos:prefLabel
  • Adsorption of pesticide benfluralin at the electrochemical interface
  • Adsorption of pesticide benfluralin at the electrochemical interface (en)
skos:notation
  • RIV/61388955:_____/13:00394481!RIV14-GA0-61388955
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GA203/09/0705), P(GA203/09/1607)
http://linked.open...iv/cisloPeriodika
  • DEC 2013
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 59594
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/13:00394481
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  • benfluralin; double layer; adsorption (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [722F6FBB6540]
http://linked.open...i/riv/nazevZdroje
  • Journal of Electroanalytical Chemistry
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  • 710
http://linked.open...iv/tvurceVysledku
  • Gál, Miroslav
  • Kolivoška, Viliam
  • Sokolová, Romana
http://linked.open...ain/vavai/riv/wos
  • 000330013900007
issn
  • 1572-6657
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.jelechem.2013.01.032
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