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  • The product of the reaction of nanofibrous anatase with ammonia in gas phase is nanofibrous cubic titanium oxynitride, c-TiO2N3. In contrary to the preparation of cubic titaniurn oxynitride from microcrystalline TiO2, requiring temperatures above 800°C, the conversion of nanofibrous TiO2 to TiO2N3 is completed at about 500°C due to its enhanced chemical reactivity. This conversion is fully reversible; the product of the back reaction is again nanofibrous Ti02. By the thermal treatment of nanofibrous anatase in H2 flow at 800°C for 2 hours the mixture of black disordered anatase, rutile and titanium suboxides was prepared. Evidently, particular phases can be synthesized simply by tuning the temperature of the treatment, which is a subject of the further research.
  • The product of the reaction of nanofibrous anatase with ammonia in gas phase is nanofibrous cubic titanium oxynitride, c-TiO2N3. In contrary to the preparation of cubic titaniurn oxynitride from microcrystalline TiO2, requiring temperatures above 800°C, the conversion of nanofibrous TiO2 to TiO2N3 is completed at about 500°C due to its enhanced chemical reactivity. This conversion is fully reversible; the product of the back reaction is again nanofibrous Ti02. By the thermal treatment of nanofibrous anatase in H2 flow at 800°C for 2 hours the mixture of black disordered anatase, rutile and titanium suboxides was prepared. Evidently, particular phases can be synthesized simply by tuning the temperature of the treatment, which is a subject of the further research. (en)
Title
  • Modification of TiO2 electronic properties by means of chemical treatment (doping)
  • Modification of TiO2 electronic properties by means of chemical treatment (doping) (en)
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  • Modification of TiO2 electronic properties by means of chemical treatment (doping)
  • Modification of TiO2 electronic properties by means of chemical treatment (doping) (en)
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  • RIV/61388955:_____/12:00393331!RIV14-AV0-61388955
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  • P(IAA400400804), P(KAN200100801), Z(AV0Z40400503)
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  • 151380
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  • RIV/61388955:_____/12:00393331
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  • titanium dioxide; doping (en)
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  • [86CC469257F5]
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  • Hnanice
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  • Prague
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  • New trends in application of photo and electro catalysis. Proceedings of the 4th Czech-Austrian workshop
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  • Kavan, Ladislav
  • Zukalová, Markéta
  • Procházka, Jan
  • Bastl, Zdeněk
  • Lásková, Barbora
  • Havlíček, D.
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  • Vysoká škola chemicko-technologická v Praze
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  • 978-80-7080-809-2
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