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Description
  • A stopped-flow method is used to study the effects of water and reactant acid anion TB = tetrakis(pentafluorophenyl)borate on the homogeneous oxygen reduction catalyzed by the protonated tetraphenylporphyrin. Observed competitive inhibition of the catalyst is linked to the DFT free energy of extraction of O2, water, and TB from the porphyrin complex.
  • A stopped-flow method is used to study the effects of water and reactant acid anion TB = tetrakis(pentafluorophenyl)borate on the homogeneous oxygen reduction catalyzed by the protonated tetraphenylporphyrin. Observed competitive inhibition of the catalyst is linked to the DFT free energy of extraction of O2, water, and TB from the porphyrin complex. (en)
Title
  • Competitive inhibition of a metal-free porphyrin oxygen-reduction catalyst by water
  • Competitive inhibition of a metal-free porphyrin oxygen-reduction catalyst by water (en)
skos:prefLabel
  • Competitive inhibition of a metal-free porphyrin oxygen-reduction catalyst by water
  • Competitive inhibition of a metal-free porphyrin oxygen-reduction catalyst by water (en)
skos:notation
  • RIV/61388955:_____/12:00376110!RIV13-GA0-61388955
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • P(GAP208/11/0697), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 34
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  • 128135
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  • RIV/61388955:_____/12:00376110
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  • metal-free porphyrin; competitive inhibition; liquid-liquid interfaces (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [94114A53AEE4]
http://linked.open...i/riv/nazevZdroje
  • Chemical Communications
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  • 48
http://linked.open...iv/tvurceVysledku
  • Langmaier, Jan
  • Záliš, Stanislav
  • Samec, Zdeněk
  • Trojánek, Antonín
http://linked.open...ain/vavai/riv/wos
  • 000302017000018
http://linked.open...n/vavai/riv/zamer
issn
  • 1359-7345
number of pages
http://bibframe.org/vocab/doi
  • 10.1039/C2CC31082A
is http://linked.open...avai/riv/vysledek of
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