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  • Polarography was first developed as an automated method of voltage-controlled electrolysis with dropping mercury electrode. The spontaneously renewed pure electrode surface provided reproducible electrochemical results which enabled scientists to work out adequate theory and rich analytical applications. The original method was then instrumentally modified in various ways. Later, hanging mercury drop was added as an alternative indicator electrode-in this way, polarography turned formally into voltammetry with mercury drop electrodes. Beside, in potential-controlled electrolysis, the mercury drop electrodes have been also used in current-controlled electrolysis (chronopotentiometry)-there, it has provided new experimental effects. Polarography has thus gradually covered a wide field of electrolytic methods based on the use of mercury electrodes, in which it continues developing.
  • Polarography was first developed as an automated method of voltage-controlled electrolysis with dropping mercury electrode. The spontaneously renewed pure electrode surface provided reproducible electrochemical results which enabled scientists to work out adequate theory and rich analytical applications. The original method was then instrumentally modified in various ways. Later, hanging mercury drop was added as an alternative indicator electrode-in this way, polarography turned formally into voltammetry with mercury drop electrodes. Beside, in potential-controlled electrolysis, the mercury drop electrodes have been also used in current-controlled electrolysis (chronopotentiometry)-there, it has provided new experimental effects. Polarography has thus gradually covered a wide field of electrolytic methods based on the use of mercury electrodes, in which it continues developing. (en)
Title
  • Polarography-past, present, and future
  • Polarography-past, present, and future (en)
skos:prefLabel
  • Polarography-past, present, and future
  • Polarography-past, present, and future (en)
skos:notation
  • RIV/61388955:_____/11:00434729!RIV15-AV0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 7-8
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 221070
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/11:00434729
http://linked.open...riv/jazykVysledku
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  • Chronopotentiometry; Current-controlled electrolysis; Dropping mercury electrode (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [52C0F0D03650]
http://linked.open...i/riv/nazevZdroje
  • Journal of Solid State Electrochemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 15
http://linked.open...iv/tvurceVysledku
  • Heyrovský, Michael
http://linked.open...ain/vavai/riv/wos
  • 000294226100042
http://linked.open...n/vavai/riv/zamer
issn
  • 1432-8488
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s10008-010-1244-0
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